Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation
The ion-associate complexes of diaveridine were prepared in a solution and studied spectrophotometrically. The bulky counter anions such as sulfonphthalein acidic dyes, namely, bromocresol green (I), bromophenol blue (II), bromothymol blue (III), bromocresol purple (IV), bromocresol blue (V), o-cres...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2018-01-01
|
| Series: | Journal of Spectroscopy |
| Online Access: | http://dx.doi.org/10.1155/2018/9269148 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832548545035501568 |
|---|---|
| author | A. L. El-Ansary N. S. Abdel-Kader A. M. Asran |
| author_facet | A. L. El-Ansary N. S. Abdel-Kader A. M. Asran |
| author_sort | A. L. El-Ansary |
| collection | DOAJ |
| description | The ion-associate complexes of diaveridine were prepared in a solution and studied spectrophotometrically. The bulky counter anions such as sulfonphthalein acidic dyes, namely, bromocresol green (I), bromophenol blue (II), bromothymol blue (III), bromocresol purple (IV), bromocresol blue (V), o-cresol red (VI), p-cresol blue (VII), and m-cresol purple (VIII) were used for ion-associate complexes formation. The optimal characteristics for the color formation and the stoichiometry of the reaction were evaluated. Spectral characteristics and stability constants of the formed ion associates are discussed in terms of nature of donor and acceptor molecular structures. The molar absorptivities and association constants for the colored complexes were evaluated using the Benesi-Hildbrand equation. Conformity to Beer’s law enabled the assay of dosage form of the drug. The molar absorptivity, specific absorptivity, Sandell sensitivity, correlation coefficient, and detection and quantification limits were also calculated. The methods were validated in terms of accuracy, specificity, precision, and linearity. Also, spectrophotometric determination of the drug in pure and pharmaceutical preparations was tested. |
| format | Article |
| id | doaj-art-6bdb342cebc342e6a6e720438d4b6666 |
| institution | Kabale University |
| issn | 2314-4920 2314-4939 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Spectroscopy |
| spelling | doaj-art-6bdb342cebc342e6a6e720438d4b66662025-02-03T06:13:50ZengWileyJournal of Spectroscopy2314-49202314-49392018-01-01201810.1155/2018/92691489269148Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes FormationA. L. El-Ansary0N. S. Abdel-Kader1A. M. Asran2Department of Chemistry, Faculty of Science, University of Cairo, Giza, EgyptDepartment of Chemistry, Faculty of Science, University of Cairo, Giza, EgyptModern Academy In Maadi For Engineering and Technology, Cairo, EgyptThe ion-associate complexes of diaveridine were prepared in a solution and studied spectrophotometrically. The bulky counter anions such as sulfonphthalein acidic dyes, namely, bromocresol green (I), bromophenol blue (II), bromothymol blue (III), bromocresol purple (IV), bromocresol blue (V), o-cresol red (VI), p-cresol blue (VII), and m-cresol purple (VIII) were used for ion-associate complexes formation. The optimal characteristics for the color formation and the stoichiometry of the reaction were evaluated. Spectral characteristics and stability constants of the formed ion associates are discussed in terms of nature of donor and acceptor molecular structures. The molar absorptivities and association constants for the colored complexes were evaluated using the Benesi-Hildbrand equation. Conformity to Beer’s law enabled the assay of dosage form of the drug. The molar absorptivity, specific absorptivity, Sandell sensitivity, correlation coefficient, and detection and quantification limits were also calculated. The methods were validated in terms of accuracy, specificity, precision, and linearity. Also, spectrophotometric determination of the drug in pure and pharmaceutical preparations was tested.http://dx.doi.org/10.1155/2018/9269148 |
| spellingShingle | A. L. El-Ansary N. S. Abdel-Kader A. M. Asran Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation Journal of Spectroscopy |
| title | Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation |
| title_full | Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation |
| title_fullStr | Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation |
| title_full_unstemmed | Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation |
| title_short | Spectrophotometric Studies on the Reaction of Diaveridine with Some Sulfonphthalein Dyes Based on Ion-Pair/Ion-Associate Complexes Formation |
| title_sort | spectrophotometric studies on the reaction of diaveridine with some sulfonphthalein dyes based on ion pair ion associate complexes formation |
| url | http://dx.doi.org/10.1155/2018/9269148 |
| work_keys_str_mv | AT alelansary spectrophotometricstudiesonthereactionofdiaveridinewithsomesulfonphthaleindyesbasedonionpairionassociatecomplexesformation AT nsabdelkader spectrophotometricstudiesonthereactionofdiaveridinewithsomesulfonphthaleindyesbasedonionpairionassociatecomplexesformation AT amasran spectrophotometricstudiesonthereactionofdiaveridinewithsomesulfonphthaleindyesbasedonionpairionassociatecomplexesformation |