Removal of trace ammonia by ionic liquids

Ammonia (NH3), a critical process gas in semiconductor production, is the second largest air pollution from semiconductor factories as well as one of PM2.5 precursors. NH3 emission standard will be regulated more strictly from current 2.5 ppm to 0.8 ppm as revealed by the 2025 semiconductor air poll...

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Main Authors: Hsu Chih-Han, Lee Wei-Chih, Chen Jiun-Jen, Kang Yu-hao
Format: Article
Language:English
Published: EDP Sciences 2025-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/20/e3sconf_icepp2024_02002.pdf
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author Hsu Chih-Han
Lee Wei-Chih
Chen Jiun-Jen
Kang Yu-hao
author_facet Hsu Chih-Han
Lee Wei-Chih
Chen Jiun-Jen
Kang Yu-hao
author_sort Hsu Chih-Han
collection DOAJ
description Ammonia (NH3), a critical process gas in semiconductor production, is the second largest air pollution from semiconductor factories as well as one of PM2.5 precursors. NH3 emission standard will be regulated more strictly from current 2.5 ppm to 0.8 ppm as revealed by the 2025 semiconductor air pollution standard draft. NH3 emission concentration was controlled using wet scrubber to achieve the regulations by adjusting pH value and increasing the water-recycling rate. However, it resulted in increased water consumption and the NH3 exhaust concentration still above emission standards (1 ppm). The purpose of this project was to develop ionic liquids which have high absorption ability to remove low NH3 concentration. The results show that IL-1 and IL-5 were both good for NH3 absorption, which the absorption capacity was greater than water. Among them, the liquid level of IL-1 will increase after the NH3 absorption test, which indicates that it has good water absorption capacity. It has the dual functions of dehumidification and ammonia removal. Furthermore, IL-5 has the best NH3 absorption ability which compared at same concentration can maintain the NH3 outlet concentration at 0 ppm for more than 351 minutes.
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issn 2267-1242
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publishDate 2025-01-01
publisher EDP Sciences
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series E3S Web of Conferences
spelling doaj-art-69dc1dfec7b64d2ca76c19b560a006d62025-08-20T03:07:06ZengEDP SciencesE3S Web of Conferences2267-12422025-01-016200200210.1051/e3sconf/202562002002e3sconf_icepp2024_02002Removal of trace ammonia by ionic liquidsHsu Chih-Han0Lee Wei-Chih1Chen Jiun-Jen2Kang Yu-hao3Green Energy and Environment Research Laboratories, Industrial Technology Research InstituteGreen Energy and Environment Research Laboratories, Industrial Technology Research InstituteGreen Energy and Environment Research Laboratories, Industrial Technology Research InstituteGreen Energy and Environment Research Laboratories, Industrial Technology Research InstituteAmmonia (NH3), a critical process gas in semiconductor production, is the second largest air pollution from semiconductor factories as well as one of PM2.5 precursors. NH3 emission standard will be regulated more strictly from current 2.5 ppm to 0.8 ppm as revealed by the 2025 semiconductor air pollution standard draft. NH3 emission concentration was controlled using wet scrubber to achieve the regulations by adjusting pH value and increasing the water-recycling rate. However, it resulted in increased water consumption and the NH3 exhaust concentration still above emission standards (1 ppm). The purpose of this project was to develop ionic liquids which have high absorption ability to remove low NH3 concentration. The results show that IL-1 and IL-5 were both good for NH3 absorption, which the absorption capacity was greater than water. Among them, the liquid level of IL-1 will increase after the NH3 absorption test, which indicates that it has good water absorption capacity. It has the dual functions of dehumidification and ammonia removal. Furthermore, IL-5 has the best NH3 absorption ability which compared at same concentration can maintain the NH3 outlet concentration at 0 ppm for more than 351 minutes.https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/20/e3sconf_icepp2024_02002.pdf
spellingShingle Hsu Chih-Han
Lee Wei-Chih
Chen Jiun-Jen
Kang Yu-hao
Removal of trace ammonia by ionic liquids
E3S Web of Conferences
title Removal of trace ammonia by ionic liquids
title_full Removal of trace ammonia by ionic liquids
title_fullStr Removal of trace ammonia by ionic liquids
title_full_unstemmed Removal of trace ammonia by ionic liquids
title_short Removal of trace ammonia by ionic liquids
title_sort removal of trace ammonia by ionic liquids
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/20/e3sconf_icepp2024_02002.pdf
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AT kangyuhao removaloftraceammoniabyionicliquids