Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation

Carbon dioxide (CO2) methanation is an essential technology for addressing global challenges such as sustainable energy storage, space exploration, and the reduction of CO2 emission. This technology has attracted broad attention in recent years. To really implement the CO2 methanation process, it is...

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Main Authors: Shuaishuai Lyu, Dejian Zhao, Hao Zhang, Hongwei Li, Fuli Wen, Qiuming Zhou, Rongjun Zhang, Yu Wu, Chaopeng Hou, Guofu Xia, Run Xu, Xingang Li
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Carbon Capture Science & Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772656825000211
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author Shuaishuai Lyu
Dejian Zhao
Hao Zhang
Hongwei Li
Fuli Wen
Qiuming Zhou
Rongjun Zhang
Yu Wu
Chaopeng Hou
Guofu Xia
Run Xu
Xingang Li
author_facet Shuaishuai Lyu
Dejian Zhao
Hao Zhang
Hongwei Li
Fuli Wen
Qiuming Zhou
Rongjun Zhang
Yu Wu
Chaopeng Hou
Guofu Xia
Run Xu
Xingang Li
author_sort Shuaishuai Lyu
collection DOAJ
description Carbon dioxide (CO2) methanation is an essential technology for addressing global challenges such as sustainable energy storage, space exploration, and the reduction of CO2 emission. This technology has attracted broad attention in recent years. To really implement the CO2 methanation process, it is crucial to design stable and highly effective catalysts. The activity and selectivity of heterogeneous catalysts can be efficiently tuned by controlling the metal-support interaction, and this strategy has been widely used in the catalyst design for CO2 methanation. In fact, the catalytic activity can be enhanced by up to ∼25 times in a CO2 methanation catalyst due to metal-support interaction. In this review, we summarize the recent progress on metal-support interaction in heterogeneous catalysts for CO2 methanation. At first, we will systemically discuss the effect of metal-support interaction in CO2 methanation catalysts, followed by a detailed introduction to its modulation strategy. Through quantitative analysis, we will point out changing chemical composition of catalyst support is the most efficient method to enhance the catalytic performance, and the primary goal of catalyst design is the modulation of electron transfer between metal particles and the support. We will also sketch the potential research direction of this promising field.
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institution Kabale University
issn 2772-6568
language English
publishDate 2025-03-01
publisher Elsevier
record_format Article
series Carbon Capture Science & Technology
spelling doaj-art-69db0430eceb4867b4e94252cbed0f022025-02-05T04:32:52ZengElsevierCarbon Capture Science & Technology2772-65682025-03-0114100381Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanationShuaishuai Lyu0Dejian Zhao1Hao Zhang2Hongwei Li3Fuli Wen4Qiuming Zhou5Rongjun Zhang6Yu Wu7Chaopeng Hou8Guofu Xia9Run Xu10Xingang Li11Sinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR China; Corresponding authors.State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Haihe Laboratory of Sustainable Chemical Transformations, Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300350, PR China; Zhejiang Institute of Tianjin University, Shaoxing, Zhejiang 312300, PR ChinaSinopec Engineering Incorporation, Beijing 100101, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR ChinaSinopec Research Institute of Petroleum Processing Co., LTD, Beijing 100083, PR China; Corresponding authors.State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Haihe Laboratory of Sustainable Chemical Transformations, Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300350, PR China; Zhejiang Institute of Tianjin University, Shaoxing, Zhejiang 312300, PR China; Corresponding author at: State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Haihe Laboratory of Sustainable Chemical Transformations, Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300350, PR China.Carbon dioxide (CO2) methanation is an essential technology for addressing global challenges such as sustainable energy storage, space exploration, and the reduction of CO2 emission. This technology has attracted broad attention in recent years. To really implement the CO2 methanation process, it is crucial to design stable and highly effective catalysts. The activity and selectivity of heterogeneous catalysts can be efficiently tuned by controlling the metal-support interaction, and this strategy has been widely used in the catalyst design for CO2 methanation. In fact, the catalytic activity can be enhanced by up to ∼25 times in a CO2 methanation catalyst due to metal-support interaction. In this review, we summarize the recent progress on metal-support interaction in heterogeneous catalysts for CO2 methanation. At first, we will systemically discuss the effect of metal-support interaction in CO2 methanation catalysts, followed by a detailed introduction to its modulation strategy. Through quantitative analysis, we will point out changing chemical composition of catalyst support is the most efficient method to enhance the catalytic performance, and the primary goal of catalyst design is the modulation of electron transfer between metal particles and the support. We will also sketch the potential research direction of this promising field.http://www.sciencedirect.com/science/article/pii/S2772656825000211Carbon dioxideMethanationCatalystHydrogenationMetal-support interaction
spellingShingle Shuaishuai Lyu
Dejian Zhao
Hao Zhang
Hongwei Li
Fuli Wen
Qiuming Zhou
Rongjun Zhang
Yu Wu
Chaopeng Hou
Guofu Xia
Run Xu
Xingang Li
Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation
Carbon Capture Science & Technology
Carbon dioxide
Methanation
Catalyst
Hydrogenation
Metal-support interaction
title Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation
title_full Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation
title_fullStr Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation
title_full_unstemmed Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation
title_short Modulation strategy and effect of metal-support interaction over catalysts for carbon dioxide methanation
title_sort modulation strategy and effect of metal support interaction over catalysts for carbon dioxide methanation
topic Carbon dioxide
Methanation
Catalyst
Hydrogenation
Metal-support interaction
url http://www.sciencedirect.com/science/article/pii/S2772656825000211
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