PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O
The electrocatalytic degradation method with PbO2/rGO electrode (anode) was chosen to treat Safranine-O waste because it was cheap and environmentally friendly. This research aimed to study the electrocatalytic efficiency of PbO2/rGO working electrode in Safranine-O removal. In this research, rGO an...
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2024-10-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
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| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/20196 |
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| author | Titin Aryani Roto Roto Mudasir Mudasir |
| author_facet | Titin Aryani Roto Roto Mudasir Mudasir |
| author_sort | Titin Aryani |
| collection | DOAJ |
| description | The electrocatalytic degradation method with PbO2/rGO electrode (anode) was chosen to treat Safranine-O waste because it was cheap and environmentally friendly. This research aimed to study the electrocatalytic efficiency of PbO2/rGO working electrode in Safranine-O removal. In this research, rGO and PbO2/rGO electrodes were synthesized and applied to Safranine-O removal through electrochemical degradation. The characterization results of the morphology of rGO are in the form of a layered structure and have the atomic composition of C (82.87%) and O (17.13%). The characterization results of PbO2/rGO are uniform particles with gaps/pores that appear relatively large. The rGO particles in the form of sheets (layers) seem to be distributed on the surface of PbO2. PbO2/rGO electrode has the atomic composition of C (87.24%), O (9.03), and Pb (3.73). The application of PbO2/rGO anode to the electrochemical degradation of Safranine-O showed good performance. It was able to perform dye removal (DE%), as well as a decrease in BOD and COD values up to >95% within 10 minutes at a concentration of 20 ppm. Application on real waste also showed the ability of dye removal, COD, and BOD reduction up to >95%. Coating or modifying the PbO2 anode with rGO can reduce the dissolution of Pb2+ ions in the solution during the electrochemical degradation. This study concluded that the PbO2/rGO electrode has improved the efficiency in Safranine-O degradation. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
| format | Article |
| id | doaj-art-681401bc5e9541468825e3e852a49b1a |
| institution | Kabale University |
| issn | 1978-2993 |
| language | English |
| publishDate | 2024-10-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj-art-681401bc5e9541468825e3e852a49b1a2025-02-02T02:54:11ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932024-10-0119348049910.9767/bcrec.201968466PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-OTitin Aryani0https://orcid.org/0000-0003-0891-0212Roto Roto1https://orcid.org/0000-0001-8163-4651Mudasir Mudasir2https://orcid.org/0000-0002-5737-7955Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Yogyakarta 55281, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Yogyakarta 55281, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Yogyakarta 55281, IndonesiaThe electrocatalytic degradation method with PbO2/rGO electrode (anode) was chosen to treat Safranine-O waste because it was cheap and environmentally friendly. This research aimed to study the electrocatalytic efficiency of PbO2/rGO working electrode in Safranine-O removal. In this research, rGO and PbO2/rGO electrodes were synthesized and applied to Safranine-O removal through electrochemical degradation. The characterization results of the morphology of rGO are in the form of a layered structure and have the atomic composition of C (82.87%) and O (17.13%). The characterization results of PbO2/rGO are uniform particles with gaps/pores that appear relatively large. The rGO particles in the form of sheets (layers) seem to be distributed on the surface of PbO2. PbO2/rGO electrode has the atomic composition of C (87.24%), O (9.03), and Pb (3.73). The application of PbO2/rGO anode to the electrochemical degradation of Safranine-O showed good performance. It was able to perform dye removal (DE%), as well as a decrease in BOD and COD values up to >95% within 10 minutes at a concentration of 20 ppm. Application on real waste also showed the ability of dye removal, COD, and BOD reduction up to >95%. Coating or modifying the PbO2 anode with rGO can reduce the dissolution of Pb2+ ions in the solution during the electrochemical degradation. This study concluded that the PbO2/rGO electrode has improved the efficiency in Safranine-O degradation. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/20196wasteelectrochemical degradationdyergolead dioxide |
| spellingShingle | Titin Aryani Roto Roto Mudasir Mudasir PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O Bulletin of Chemical Reaction Engineering & Catalysis waste electrochemical degradation dye rgo lead dioxide |
| title | PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O |
| title_full | PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O |
| title_fullStr | PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O |
| title_full_unstemmed | PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O |
| title_short | PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O |
| title_sort | pbo2 rgo electrode as a superior and efficient anode in electrocatalytic degradation of safranine o |
| topic | waste electrochemical degradation dye rgo lead dioxide |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/20196 |
| work_keys_str_mv | AT titinaryani pbo2rgoelectrodeasasuperiorandefficientanodeinelectrocatalyticdegradationofsafranineo AT rotoroto pbo2rgoelectrodeasasuperiorandefficientanodeinelectrocatalyticdegradationofsafranineo AT mudasirmudasir pbo2rgoelectrodeasasuperiorandefficientanodeinelectrocatalyticdegradationofsafranineo |