Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry

Abstract The polar regions are biologically productive and play a critical role in regional and global biogeochemical cycling. A key nutrient is dissolved silicon, required for the growth of siliceous phytoplankton, diatoms, which form an important component of polar ecosystems. Glacial weathering i...

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Main Authors: Katharine R. Hendry, Felipe Sales de Freitas, Sandra Arndt, Alexander Beaton, Lisa Friberg, Jade E. Hatton, Jonathan R. Hawkings, Rhiannon L. Jones, Jeffrey W. Krause, Lorenz Meire, Hong Chin Ng, Helena Pryer, Sarah Tingey, Sebastiaan J. van de Velde, Jemma Wadham, Tong Wang, E. Malcolm S. Woodward
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Communications Earth & Environment
Online Access:https://doi.org/10.1038/s43247-025-02264-7
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author Katharine R. Hendry
Felipe Sales de Freitas
Sandra Arndt
Alexander Beaton
Lisa Friberg
Jade E. Hatton
Jonathan R. Hawkings
Rhiannon L. Jones
Jeffrey W. Krause
Lorenz Meire
Hong Chin Ng
Helena Pryer
Sarah Tingey
Sebastiaan J. van de Velde
Jemma Wadham
Tong Wang
E. Malcolm S. Woodward
author_facet Katharine R. Hendry
Felipe Sales de Freitas
Sandra Arndt
Alexander Beaton
Lisa Friberg
Jade E. Hatton
Jonathan R. Hawkings
Rhiannon L. Jones
Jeffrey W. Krause
Lorenz Meire
Hong Chin Ng
Helena Pryer
Sarah Tingey
Sebastiaan J. van de Velde
Jemma Wadham
Tong Wang
E. Malcolm S. Woodward
author_sort Katharine R. Hendry
collection DOAJ
description Abstract The polar regions are biologically productive and play a critical role in regional and global biogeochemical cycling. A key nutrient is dissolved silicon, required for the growth of siliceous phytoplankton, diatoms, which form an important component of polar ecosystems. Glacial weathering is thought to be an important dissolved silicon source to coastal waters, especially critical in regions experiencing seasonal silicon limitation of diatom growth. However, complex physical and biogeochemical interactions in fjords and coastal regions modulate the downstream supply of dissolved and particulate nutrients, including silicon. Here, we review the biogeochemical complexities of glaciated margins and the insights into this system that silicon isotope geochemistry offer. We show that stable and radioisotopic measurements and biogeochemical numerical modelling provide a quantitative mechanistic understanding of subglacial silica mobilisation and its cycling across the land-ocean continuum. Subglacial weathering produces isotopically light amorphous silica, which dissolves in seawater to release dissolved silicon. Our findings show that isotopically light, detrital silica, likely containing glacial material, reaches the ocean and there could support a substantial proportion of diatom productivity, especially in the Arctic. Outstanding questions about silicon cycling in these crucial environments will be addressed through novel and cross-discipline approaches that overcome traditionally viewed ecosystem boundaries.
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spelling doaj-art-67a37f5fd21742c38dd9671f5ce7348a2025-08-20T02:17:52ZengNature PortfolioCommunications Earth & Environment2662-44352025-04-016111210.1038/s43247-025-02264-7Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistryKatharine R. Hendry0Felipe Sales de Freitas1Sandra Arndt2Alexander Beaton3Lisa Friberg4Jade E. Hatton5Jonathan R. Hawkings6Rhiannon L. Jones7Jeffrey W. Krause8Lorenz Meire9Hong Chin Ng10Helena Pryer11Sarah Tingey12Sebastiaan J. van de Velde13Jemma Wadham14Tong Wang15E. Malcolm S. Woodward16British Antarctic Survey, High CrossBGeosys, Department of Geosciences, Université libre de BruxellesBGeosys, Department of Geosciences, Université libre de BruxellesNational Oceanography Centre SouthamptonSchool of Earth Sciences, University of BristolSchool of Earth Sciences, University of BristoliC3: Centre for ice, Cryosphere, Carbon and Climate, Department of Geosciences, UiT The Arctic University of NorwayBritish Antarctic Survey, High CrossDauphin Island Sea LabGreenland Climate Research Centre, Greenland Institute of Natural ResourcesSchool of Earth Sciences, University of BristolDepartment of Earth Sciences, University of CambridgeiC3: Centre for ice, Cryosphere, Carbon and Climate, Department of Geosciences, UiT The Arctic University of NorwayDepartment of Biology, University of AntwerpiC3: Centre for ice, Cryosphere, Carbon and Climate, Department of Geosciences, UiT The Arctic University of NorwaySchool of Earth Sciences, University of BristolPlymouth Marine Laboratory, Prospect Place, The HoeAbstract The polar regions are biologically productive and play a critical role in regional and global biogeochemical cycling. A key nutrient is dissolved silicon, required for the growth of siliceous phytoplankton, diatoms, which form an important component of polar ecosystems. Glacial weathering is thought to be an important dissolved silicon source to coastal waters, especially critical in regions experiencing seasonal silicon limitation of diatom growth. However, complex physical and biogeochemical interactions in fjords and coastal regions modulate the downstream supply of dissolved and particulate nutrients, including silicon. Here, we review the biogeochemical complexities of glaciated margins and the insights into this system that silicon isotope geochemistry offer. We show that stable and radioisotopic measurements and biogeochemical numerical modelling provide a quantitative mechanistic understanding of subglacial silica mobilisation and its cycling across the land-ocean continuum. Subglacial weathering produces isotopically light amorphous silica, which dissolves in seawater to release dissolved silicon. Our findings show that isotopically light, detrital silica, likely containing glacial material, reaches the ocean and there could support a substantial proportion of diatom productivity, especially in the Arctic. Outstanding questions about silicon cycling in these crucial environments will be addressed through novel and cross-discipline approaches that overcome traditionally viewed ecosystem boundaries.https://doi.org/10.1038/s43247-025-02264-7
spellingShingle Katharine R. Hendry
Felipe Sales de Freitas
Sandra Arndt
Alexander Beaton
Lisa Friberg
Jade E. Hatton
Jonathan R. Hawkings
Rhiannon L. Jones
Jeffrey W. Krause
Lorenz Meire
Hong Chin Ng
Helena Pryer
Sarah Tingey
Sebastiaan J. van de Velde
Jemma Wadham
Tong Wang
E. Malcolm S. Woodward
Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
Communications Earth & Environment
title Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
title_full Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
title_fullStr Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
title_full_unstemmed Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
title_short Insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
title_sort insights into silicon cycling from ice sheet to coastal ocean from isotope geochemistry
url https://doi.org/10.1038/s43247-025-02264-7
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