Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces
The article is devoted to the study of the adhesive interaction of restorative compositions with shell limestone as a highly porous material of complex structure. The key physicochemical and mechanical factors determining adhesion are analyzed, including molecular forces, hydrogen bonds, electrostat...
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| Format: | Article |
| Language: | English |
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University North
2025-01-01
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| Series: | Tehnički Glasnik |
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| Online Access: | https://hrcak.srce.hr/file/473485 |
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| author | Andrii Kolesnykov Mykola Khlytsov Svitlana Semenova Mario Šercer |
| author_facet | Andrii Kolesnykov Mykola Khlytsov Svitlana Semenova Mario Šercer |
| author_sort | Andrii Kolesnykov |
| collection | DOAJ |
| description | The article is devoted to the study of the adhesive interaction of restorative compositions with shell limestone as a highly porous material of complex structure. The key physicochemical and mechanical factors determining adhesion are analyzed, including molecular forces, hydrogen bonds, electrostatic interactions, acid-base interactions, as well as the effect of humidity on adhesion. Elements of fractal geometry are used to describe the processes of adaptation of compositions to porous surfaces, a criterion of ideal adhesive contact is introduced. Models of structure formation are considered, including the Smoluchowski equation, diffusion-limited and cluster-cluster aggregation. It is shown how optimization of the restorative composition due to the selection of the necessary fractal parameters can improve its adhesive characteristics. Recommendations are given for the use of various methods for optimizing adhesion processes in restoration. It is also possible to use the obtained results in modern additive technologies. |
| format | Article |
| id | doaj-art-671e619526eb408ebe963f605b225db1 |
| institution | Kabale University |
| issn | 1846-6168 1848-5588 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | University North |
| record_format | Article |
| series | Tehnički Glasnik |
| spelling | doaj-art-671e619526eb408ebe963f605b225db12025-02-06T15:20:17ZengUniversity NorthTehnički Glasnik1846-61681848-55882025-01-011919410210.31803/tg-20250108082640Investigation and Optimization of Adhesive Structure Formation on Shell Limestone SurfacesAndrii Kolesnykov0Mykola Khlytsov1Svitlana Semenova2Mario Šercer3Odessa State Academy of Civil Engineering and Architecture, Construction and Technological Institute, Department of Chemistry and Ecology, Didrihsona st., 4, 65029 Odesa, UkraineOdessa State Academy of Civil Engineering and Architecture, Construction and Technological Institute, Department of Processes and Apparatuses in the Technology of Building Materials, Didrihsona st., 4, 65029 Odesa, UkraineOdessa State Academy of Civil Engineering and Architecture, Construction and Technological Institute, Department of Chemistry and Ecology, Didrihsona st., 4, 65029 Odesa, UkraineDevelopment and Training Centre for the Metal Industry - Metal Centre Čakovec, Bana Josipa Jelačića 22 D, 40000 Čakovec, CroatiaThe article is devoted to the study of the adhesive interaction of restorative compositions with shell limestone as a highly porous material of complex structure. The key physicochemical and mechanical factors determining adhesion are analyzed, including molecular forces, hydrogen bonds, electrostatic interactions, acid-base interactions, as well as the effect of humidity on adhesion. Elements of fractal geometry are used to describe the processes of adaptation of compositions to porous surfaces, a criterion of ideal adhesive contact is introduced. Models of structure formation are considered, including the Smoluchowski equation, diffusion-limited and cluster-cluster aggregation. It is shown how optimization of the restorative composition due to the selection of the necessary fractal parameters can improve its adhesive characteristics. Recommendations are given for the use of various methods for optimizing adhesion processes in restoration. It is also possible to use the obtained results in modern additive technologies.https://hrcak.srce.hr/file/473485adhesionfractal dimensionporous structurerestorative compositionsshell limestonestructure formation |
| spellingShingle | Andrii Kolesnykov Mykola Khlytsov Svitlana Semenova Mario Šercer Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces Tehnički Glasnik adhesion fractal dimension porous structure restorative compositions shell limestone structure formation |
| title | Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces |
| title_full | Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces |
| title_fullStr | Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces |
| title_full_unstemmed | Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces |
| title_short | Investigation and Optimization of Adhesive Structure Formation on Shell Limestone Surfaces |
| title_sort | investigation and optimization of adhesive structure formation on shell limestone surfaces |
| topic | adhesion fractal dimension porous structure restorative compositions shell limestone structure formation |
| url | https://hrcak.srce.hr/file/473485 |
| work_keys_str_mv | AT andriikolesnykov investigationandoptimizationofadhesivestructureformationonshelllimestonesurfaces AT mykolakhlytsov investigationandoptimizationofadhesivestructureformationonshelllimestonesurfaces AT svitlanasemenova investigationandoptimizationofadhesivestructureformationonshelllimestonesurfaces AT mariosercer investigationandoptimizationofadhesivestructureformationonshelllimestonesurfaces |