Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing

Columnar nanostructured TiO2 films were prepared by sputtering Ti target in pure argon with glancing angle deposition (GLAD) and subsequent annealing at 400°C for different hours in air. Compared with sputtering TiO2 target directly, sputtering Ti target can be carried out under much lower base pres...

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Main Authors: Zhengcao Li, Liping Xing, Zhengjun Zhang
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2012/413638
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author Zhengcao Li
Liping Xing
Zhengjun Zhang
author_facet Zhengcao Li
Liping Xing
Zhengjun Zhang
author_sort Zhengcao Li
collection DOAJ
description Columnar nanostructured TiO2 films were prepared by sputtering Ti target in pure argon with glancing angle deposition (GLAD) and subsequent annealing at 400°C for different hours in air. Compared with sputtering TiO2 target directly, sputtering Ti target can be carried out under much lower base pressure, which contributes to obtaining discrete columnar nanostructures. In the present study, TiO2 films obtained by annealing Ti films for different hours all kept discrete columnar structures as the Ti films deposited in GLAD regime. The longer the annealing time was, the better the phase transition accomplished from Ti to TiO2 (a mixture of rutile and anatase), and the better it crystallized. In addition, those TiO2 films performed photocatalytic decolorization effectively and showed a law changing over annealing time under UV light irradiation towards methyl orange, which demonstrated the potential applications for treatment of effluent.
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institution Kabale University
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publishDate 2012-01-01
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series Advances in Materials Science and Engineering
spelling doaj-art-66cfc65638924a0280922a09f6e4b6c02025-02-03T01:09:40ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422012-01-01201210.1155/2012/413638413638Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent AnnealingZhengcao Li0Liping Xing1Zhengjun Zhang2Advanced Materials Laboratory, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, ChinaAdvanced Materials Laboratory, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, ChinaAdvanced Materials Laboratory, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, ChinaColumnar nanostructured TiO2 films were prepared by sputtering Ti target in pure argon with glancing angle deposition (GLAD) and subsequent annealing at 400°C for different hours in air. Compared with sputtering TiO2 target directly, sputtering Ti target can be carried out under much lower base pressure, which contributes to obtaining discrete columnar nanostructures. In the present study, TiO2 films obtained by annealing Ti films for different hours all kept discrete columnar structures as the Ti films deposited in GLAD regime. The longer the annealing time was, the better the phase transition accomplished from Ti to TiO2 (a mixture of rutile and anatase), and the better it crystallized. In addition, those TiO2 films performed photocatalytic decolorization effectively and showed a law changing over annealing time under UV light irradiation towards methyl orange, which demonstrated the potential applications for treatment of effluent.http://dx.doi.org/10.1155/2012/413638
spellingShingle Zhengcao Li
Liping Xing
Zhengjun Zhang
Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing
Advances in Materials Science and Engineering
title Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing
title_full Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing
title_fullStr Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing
title_full_unstemmed Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing
title_short Photocatalytic Properties of Columnar Nanostructured TiO2 Films Fabricated by Sputtering Ti and Subsequent Annealing
title_sort photocatalytic properties of columnar nanostructured tio2 films fabricated by sputtering ti and subsequent annealing
url http://dx.doi.org/10.1155/2012/413638
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AT zhengjunzhang photocatalyticpropertiesofcolumnarnanostructuredtio2filmsfabricatedbysputteringtiandsubsequentannealing