Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study

In this study,  thin films of pure and aluminum (Al)-doped zinc oxide/polymethyl methacrylate (ZnO/PMMA) with two different amounts (5% and 7%) using the sol-gel and spin coating methods were created and then heated at two temperatures (450 and 750°C). Many characteristics were used to analyze the...

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Main Authors: Abdellah Elkaiem, Omar Boukraa
Format: Article
Language:English
Published: University of Baghdad 2025-06-01
Series:Iraqi Journal of Physics
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Online Access:https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1467
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author Abdellah Elkaiem
Omar Boukraa
author_facet Abdellah Elkaiem
Omar Boukraa
author_sort Abdellah Elkaiem
collection DOAJ
description In this study,  thin films of pure and aluminum (Al)-doped zinc oxide/polymethyl methacrylate (ZnO/PMMA) with two different amounts (5% and 7%) using the sol-gel and spin coating methods were created and then heated at two temperatures (450 and 750°C). Many characteristics were used to analyze the resulting samples, including X-ray diffraction (XRD), UV-visible, and infrared (IR) absorption spectroscopy. The X-ray diffraction analysis of the samples indicated that they formed a hexagonal structure of ZnO known as wurtzite, with a preferred direction labelled as (101). UV-visible analysis of the specimens' optical characteristics has helped calculate the gap energy using the Tauc method. The energy value is 4.12 eV. The optical characteristics of the samples were analyzed by the Fourier Transform Infrared (FTIR), which shows the presence of absorption peaks attributed to the existence of the new phase that cannot be observed through the X-rays, which is a phase of spinel zinc aluminate  (ZnAl2O4).
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spelling doaj-art-663ae2ba39c7434e9d9250d3ccafc00d2025-08-20T02:06:22ZengUniversity of BaghdadIraqi Journal of Physics2070-40032664-55482025-06-0123210.30723/ijp.v23i2.1467Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical StudyAbdellah Elkaiem0Omar Boukraa 1University of Ouargla, Faculty of Mathematics and Material Sciences, Laboratory for the Development of New and Renewable Energies in Arid and Saharan Zones, Ouargla 30000, AlgeriUniversity of Ouargla, Faculty of Mathematics and Material Sciences, Laboratory for the Development of New and Renewable Energies in Arid and Saharan Zones, Ouargla 30000, Algeria In this study,  thin films of pure and aluminum (Al)-doped zinc oxide/polymethyl methacrylate (ZnO/PMMA) with two different amounts (5% and 7%) using the sol-gel and spin coating methods were created and then heated at two temperatures (450 and 750°C). Many characteristics were used to analyze the resulting samples, including X-ray diffraction (XRD), UV-visible, and infrared (IR) absorption spectroscopy. The X-ray diffraction analysis of the samples indicated that they formed a hexagonal structure of ZnO known as wurtzite, with a preferred direction labelled as (101). UV-visible analysis of the specimens' optical characteristics has helped calculate the gap energy using the Tauc method. The energy value is 4.12 eV. The optical characteristics of the samples were analyzed by the Fourier Transform Infrared (FTIR), which shows the presence of absorption peaks attributed to the existence of the new phase that cannot be observed through the X-rays, which is a phase of spinel zinc aluminate  (ZnAl2O4). https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1467NanopowderThin Films of ZnOSol-GelPhase SpinelZnAl2O4
spellingShingle Abdellah Elkaiem
Omar Boukraa
Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study
Iraqi Journal of Physics
Nanopowder
Thin Films of ZnO
Sol-Gel
Phase Spinel
ZnAl2O4
title Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study
title_full Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study
title_fullStr Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study
title_full_unstemmed Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study
title_short Contribution to the Development of Nano-Composite Materials Based on ZnO and Polymethyl Methacrylate Structural and Optical Study
title_sort contribution to the development of nano composite materials based on zno and polymethyl methacrylate structural and optical study
topic Nanopowder
Thin Films of ZnO
Sol-Gel
Phase Spinel
ZnAl2O4
url https://ijp.uobaghdad.edu.iq/index.php/physics/article/view/1467
work_keys_str_mv AT abdellahelkaiem contributiontothedevelopmentofnanocompositematerialsbasedonznoandpolymethylmethacrylatestructuralandopticalstudy
AT omarboukraa contributiontothedevelopmentofnanocompositematerialsbasedonznoandpolymethylmethacrylatestructuralandopticalstudy