Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process

In this study, ceria and ceria-zirconia solid solutions were tested as catalyst for the treatment of landfill leachate with a Fenton-like process. The catalysts considered in this work were pure ceria and ceria-zirconia solid solutions as well as iron-doped samples. All the catalysts were extensivel...

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Main Authors: E. Aneggi, V. Cabbai, A. Trovarelli, D. Goi
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/694721
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author E. Aneggi
V. Cabbai
A. Trovarelli
D. Goi
author_facet E. Aneggi
V. Cabbai
A. Trovarelli
D. Goi
author_sort E. Aneggi
collection DOAJ
description In this study, ceria and ceria-zirconia solid solutions were tested as catalyst for the treatment of landfill leachate with a Fenton-like process. The catalysts considered in this work were pure ceria and ceria-zirconia solid solutions as well as iron-doped samples. All the catalysts were extensively characterized and applied in batch Fenton-like reactions by a close batch system, the COD (chemical oxygen demand) and TOC (total organic carbon) parameters were carried out before and after the treatments in order to assay oxidative abatement. Results show a measurable improvement of the TOC and COD abatement using ceria-based catalysts in Fenton-like process and the best result was achieved for iron-doped ceria-zirconia solid solution. Our outcomes point out that heterogeneous Fenton technique could be effectively used for the treatment of landfill leachate and it is worth to be the object of further investigations.
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institution Kabale University
issn 1110-662X
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series International Journal of Photoenergy
spelling doaj-art-65cc31237a2a40adaf010d6a8ab6562a2025-02-03T01:07:53ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/694721694721Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton ProcessE. Aneggi0V. Cabbai1A. Trovarelli2D. Goi3Department of Chemistry, Physics and Environment, University of Udine, Via del Cotonificio, 108-331100 Udine, ItalyDepartment of Chemistry, Physics and Environment, University of Udine, Via del Cotonificio, 108-331100 Udine, ItalyCatalysis Group, Department of Chemistry, Physics and Environment, University of Udine, Via del Cotonificio, 108-331100 Udine, ItalyCivil Environmental Group, Department of Chemistry, Physics and Environment, University of Udine, Via del Cotonificio, 108-331100 Udine, ItalyIn this study, ceria and ceria-zirconia solid solutions were tested as catalyst for the treatment of landfill leachate with a Fenton-like process. The catalysts considered in this work were pure ceria and ceria-zirconia solid solutions as well as iron-doped samples. All the catalysts were extensively characterized and applied in batch Fenton-like reactions by a close batch system, the COD (chemical oxygen demand) and TOC (total organic carbon) parameters were carried out before and after the treatments in order to assay oxidative abatement. Results show a measurable improvement of the TOC and COD abatement using ceria-based catalysts in Fenton-like process and the best result was achieved for iron-doped ceria-zirconia solid solution. Our outcomes point out that heterogeneous Fenton technique could be effectively used for the treatment of landfill leachate and it is worth to be the object of further investigations.http://dx.doi.org/10.1155/2012/694721
spellingShingle E. Aneggi
V. Cabbai
A. Trovarelli
D. Goi
Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process
International Journal of Photoenergy
title Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process
title_full Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process
title_fullStr Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process
title_full_unstemmed Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process
title_short Potential of Ceria-Based Catalysts for the Oxidation of Landfill Leachate by Heterogeneous Fenton Process
title_sort potential of ceria based catalysts for the oxidation of landfill leachate by heterogeneous fenton process
url http://dx.doi.org/10.1155/2012/694721
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AT vcabbai potentialofceriabasedcatalystsfortheoxidationoflandfillleachatebyheterogeneousfentonprocess
AT atrovarelli potentialofceriabasedcatalystsfortheoxidationoflandfillleachatebyheterogeneousfentonprocess
AT dgoi potentialofceriabasedcatalystsfortheoxidationoflandfillleachatebyheterogeneousfentonprocess