Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors

When a sample of semiconducting material is illuminated by monochromatic light, in which the photon energy is higher than the energy gap of the semiconductor, part of the absorbed electromagnetic energy is spent on the generation of pairs of quasi-free charge carriers that are bound by Coulomb attra...

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Main Authors: Slobodanka Galovic, Katarina Djordjevic, Milica Dragas, Dejan Milicevic, Edin Suljovrujic
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Mathematics
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Online Access:https://www.mdpi.com/2227-7390/13/2/258
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author Slobodanka Galovic
Katarina Djordjevic
Milica Dragas
Dejan Milicevic
Edin Suljovrujic
author_facet Slobodanka Galovic
Katarina Djordjevic
Milica Dragas
Dejan Milicevic
Edin Suljovrujic
author_sort Slobodanka Galovic
collection DOAJ
description When a sample of semiconducting material is illuminated by monochromatic light, in which the photon energy is higher than the energy gap of the semiconductor, part of the absorbed electromagnetic energy is spent on the generation of pairs of quasi-free charge carriers that are bound by Coulomb attraction. Photo-generated pairs diffuse through the material as a whole according to the density gradients established, carrying part of the excitation energy and charge through the semiconducting sample. This energy is indirectly transformed into heat, where the excess negatively charged electron recombines with a positively charged hole and causes additional local heating of the lattice. The dynamic of the photoexcited charge carrier is described by a non-linear partial differential equation of ambipolar diffusion. In moderate doped semiconductors with a low-level injection of charge carriers, ambipolar transport can be reduced to the linear parabolic partial differential equation for the transport of minority carriers. In this paper, we calculated the spectral function of the photoinduced charge carrier distribution based on an approximation of low-level injection. Using the calculated distribution and inverse Laplace transform, the dynamics of recombination photoinduced heat sources at the surfaces of semiconducting samples were studied for pulse optical excitations of very short and very long durations. It was shown that the photoexcited charge carriers affect semiconductor heating depending on the pulse duration, velocity of surface recombination, lifetime of charge carriers, and their diffusion coefficient.
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publishDate 2025-01-01
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spelling doaj-art-65bbc4a7dc1d4b8a858efa5f135d1e862025-01-24T13:39:55ZengMDPI AGMathematics2227-73902025-01-0113225810.3390/math13020258Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped SemiconductorsSlobodanka Galovic0Katarina Djordjevic1Milica Dragas2Dejan Milicevic3Edin Suljovrujic4Vinca Institute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovica Alasa 12-14, P.O. Box 522, 11001 Belgrade, SerbiaVinca Institute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovica Alasa 12-14, P.O. Box 522, 11001 Belgrade, SerbiaFaculty of Philosophy, University of East Sarajevo, Vuka Karadžića 30, 71126 Lukavica, Republic of Srpska, Bosnia and HerzegovinaVinca Institute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovica Alasa 12-14, P.O. Box 522, 11001 Belgrade, SerbiaVinca Institute of Nuclear Sciences—National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovica Alasa 12-14, P.O. Box 522, 11001 Belgrade, SerbiaWhen a sample of semiconducting material is illuminated by monochromatic light, in which the photon energy is higher than the energy gap of the semiconductor, part of the absorbed electromagnetic energy is spent on the generation of pairs of quasi-free charge carriers that are bound by Coulomb attraction. Photo-generated pairs diffuse through the material as a whole according to the density gradients established, carrying part of the excitation energy and charge through the semiconducting sample. This energy is indirectly transformed into heat, where the excess negatively charged electron recombines with a positively charged hole and causes additional local heating of the lattice. The dynamic of the photoexcited charge carrier is described by a non-linear partial differential equation of ambipolar diffusion. In moderate doped semiconductors with a low-level injection of charge carriers, ambipolar transport can be reduced to the linear parabolic partial differential equation for the transport of minority carriers. In this paper, we calculated the spectral function of the photoinduced charge carrier distribution based on an approximation of low-level injection. Using the calculated distribution and inverse Laplace transform, the dynamics of recombination photoinduced heat sources at the surfaces of semiconducting samples were studied for pulse optical excitations of very short and very long durations. It was shown that the photoexcited charge carriers affect semiconductor heating depending on the pulse duration, velocity of surface recombination, lifetime of charge carriers, and their diffusion coefficient.https://www.mdpi.com/2227-7390/13/2/258transport of chargeambipolar diffusionnon-linear dynamic problemlow-level injectionrecombination heat sourcesparabolic partial differential equation
spellingShingle Slobodanka Galovic
Katarina Djordjevic
Milica Dragas
Dejan Milicevic
Edin Suljovrujic
Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors
Mathematics
transport of charge
ambipolar diffusion
non-linear dynamic problem
low-level injection
recombination heat sources
parabolic partial differential equation
title Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors
title_full Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors
title_fullStr Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors
title_full_unstemmed Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors
title_short Dynamics of Photoinduced Charge Carrier and Photothermal Effect in Pulse-Illuminated Narrow Gap and Moderate Doped Semiconductors
title_sort dynamics of photoinduced charge carrier and photothermal effect in pulse illuminated narrow gap and moderate doped semiconductors
topic transport of charge
ambipolar diffusion
non-linear dynamic problem
low-level injection
recombination heat sources
parabolic partial differential equation
url https://www.mdpi.com/2227-7390/13/2/258
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