Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient

Fracture toughness is a critical indicator for the application of NiTi alloys in medical fields. We propose to enhance the fracture toughness of NiTi alloys by controlling the spatial grain size (GS) gradient. Utilizing rolling processes and heat treatment technology, three categories of NiTi alloys...

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Main Authors: Kai Huang, Zhongzheng Deng, Hao Yin
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/2/125
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author Kai Huang
Zhongzheng Deng
Hao Yin
author_facet Kai Huang
Zhongzheng Deng
Hao Yin
author_sort Kai Huang
collection DOAJ
description Fracture toughness is a critical indicator for the application of NiTi alloys in medical fields. We propose to enhance the fracture toughness of NiTi alloys by controlling the spatial grain size (GS) gradient. Utilizing rolling processes and heat treatment technology, three categories of NiTi alloys with distinct spatial GS distributions were fabricated and subsequently examined through multi-field synchronous fracture tests. It is found that the one with a locally ultra-high GS gradient (20 nm−3.4 μm) has significantly enhanced fracture toughness, which is as high as 412% of that of the normally distributed nano-grains with an average GS of 8 nm and 178% of that of the coarse-grains with an average GS of 100 nm. Theoretical analysis reveals that in such a gradient structure, phase transition in the coarse-grained matrix greatly absorbs the surface energy of subcritical and stable propagation. Meanwhile, the locally non-uniform GS distribution leads to deviation and tortuosity of the crack path, increasing the critical fracture stress. Furthermore, the nanocrystalline clusters distributed in the form of network nodes reduce the stress intensity factor due to their higher elastic modulus compared to the coarse-grained matrix. This work provides guidance for developing new gradient nanostructured NiTi alloys with high fracture toughness.
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spelling doaj-art-658938f3bfa14b0dbf3bc60508a7db1e2025-01-24T13:44:14ZengMDPI AGNanomaterials2079-49912025-01-0115212510.3390/nano15020125Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size GradientKai Huang0Zhongzheng Deng1Hao Yin2School of Civil Engineering, Wuhan University, Wuhan 430072, ChinaDepartment of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Hong Kong, ChinaSchool of Civil Engineering, Wuhan University, Wuhan 430072, ChinaFracture toughness is a critical indicator for the application of NiTi alloys in medical fields. We propose to enhance the fracture toughness of NiTi alloys by controlling the spatial grain size (GS) gradient. Utilizing rolling processes and heat treatment technology, three categories of NiTi alloys with distinct spatial GS distributions were fabricated and subsequently examined through multi-field synchronous fracture tests. It is found that the one with a locally ultra-high GS gradient (20 nm−3.4 μm) has significantly enhanced fracture toughness, which is as high as 412% of that of the normally distributed nano-grains with an average GS of 8 nm and 178% of that of the coarse-grains with an average GS of 100 nm. Theoretical analysis reveals that in such a gradient structure, phase transition in the coarse-grained matrix greatly absorbs the surface energy of subcritical and stable propagation. Meanwhile, the locally non-uniform GS distribution leads to deviation and tortuosity of the crack path, increasing the critical fracture stress. Furthermore, the nanocrystalline clusters distributed in the form of network nodes reduce the stress intensity factor due to their higher elastic modulus compared to the coarse-grained matrix. This work provides guidance for developing new gradient nanostructured NiTi alloys with high fracture toughness.https://www.mdpi.com/2079-4991/15/2/125NiTi alloysfracture toughnessfracture behaviorgrain sizegradient
spellingShingle Kai Huang
Zhongzheng Deng
Hao Yin
Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient
Nanomaterials
NiTi alloys
fracture toughness
fracture behavior
grain size
gradient
title Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient
title_full Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient
title_fullStr Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient
title_full_unstemmed Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient
title_short Enhancement of Fracture Toughness of NiTi Alloy by Controlling Grain Size Gradient
title_sort enhancement of fracture toughness of niti alloy by controlling grain size gradient
topic NiTi alloys
fracture toughness
fracture behavior
grain size
gradient
url https://www.mdpi.com/2079-4991/15/2/125
work_keys_str_mv AT kaihuang enhancementoffracturetoughnessofnitialloybycontrollinggrainsizegradient
AT zhongzhengdeng enhancementoffracturetoughnessofnitialloybycontrollinggrainsizegradient
AT haoyin enhancementoffracturetoughnessofnitialloybycontrollinggrainsizegradient