MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles

The growing demand for energy storage has drawn considerable attention to devices such as supercapacitors, which currently lack high energy density but depict high power density and long cycle life. In this work, we have synthesized La0.3Sr0.7Ti0.5Fe0.5O3 (LSTF) nanoparticles and Ti3C2-MXene-modifie...

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Main Authors: Muhammad Qaiser Manzoor, Syed Irfan, null Anwar-ul-Haq, Xuyang Shi
Format: Article
Language:English
Published: Wiley 2024-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2024/8297902
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author Muhammad Qaiser Manzoor
Syed Irfan
null Anwar-ul-Haq
Xuyang Shi
author_facet Muhammad Qaiser Manzoor
Syed Irfan
null Anwar-ul-Haq
Xuyang Shi
author_sort Muhammad Qaiser Manzoor
collection DOAJ
description The growing demand for energy storage has drawn considerable attention to devices such as supercapacitors, which currently lack high energy density but depict high power density and long cycle life. In this work, we have synthesized La0.3Sr0.7Ti0.5Fe0.5O3 (LSTF) nanoparticles and Ti3C2-MXene-modified LSTF nanoparticle hybrid to study the effect of MXene on electrochemical properties of the nanoparticles. The X-ray diffraction (XRD) and Raman spectroscopy analysis showed that the hybrid structure retained all the major peaks of the nanoparticles and the MXene, which showed its successful synthesis. The morphological analysis was done utilizing scanning electron microscopy (SEM), which verified that the nanoparticles had been adsorbed and/or agglomerated onto the MXene sheets. The electrochemical analysis showed that with the addition of MXene into the nanoparticles, the specific capacitance tested via cyclic voltammetry increased from 225.6 Fg‒1 to 419.5 Fg‒1 at the scan rate of 2 mVs-1, which makes the hybrid a suitable electrode material for supercapacitors. The value of specific capacitance for the hybrid tested via galvanostatic charge-discharge showed an increased value of 23 Fg‒1 at the current density of 1 Ag-1. The Fourier transform infrared (FTIR) spectroscopy showed that the hybrid contains –O functional groups coming from MXene, which causes an increase in electrochemical activity at the electrode surface, resulting in enhanced capacitance.
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issn 1687-9511
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spelling doaj-art-658684a2951f451b9380303e1580b6d82025-02-03T11:54:02ZengWileyJournal of Nanotechnology1687-95112024-01-01202410.1155/2024/8297902MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium NanoparticlesMuhammad Qaiser Manzoor0Syed Irfan1null Anwar-ul-Haq2Xuyang Shi3Department of PhysicsState Key Laboratory of Environment-Friendly Energy MaterialsDepartment of PhysicsSchool of Information EngineeringThe growing demand for energy storage has drawn considerable attention to devices such as supercapacitors, which currently lack high energy density but depict high power density and long cycle life. In this work, we have synthesized La0.3Sr0.7Ti0.5Fe0.5O3 (LSTF) nanoparticles and Ti3C2-MXene-modified LSTF nanoparticle hybrid to study the effect of MXene on electrochemical properties of the nanoparticles. The X-ray diffraction (XRD) and Raman spectroscopy analysis showed that the hybrid structure retained all the major peaks of the nanoparticles and the MXene, which showed its successful synthesis. The morphological analysis was done utilizing scanning electron microscopy (SEM), which verified that the nanoparticles had been adsorbed and/or agglomerated onto the MXene sheets. The electrochemical analysis showed that with the addition of MXene into the nanoparticles, the specific capacitance tested via cyclic voltammetry increased from 225.6 Fg‒1 to 419.5 Fg‒1 at the scan rate of 2 mVs-1, which makes the hybrid a suitable electrode material for supercapacitors. The value of specific capacitance for the hybrid tested via galvanostatic charge-discharge showed an increased value of 23 Fg‒1 at the current density of 1 Ag-1. The Fourier transform infrared (FTIR) spectroscopy showed that the hybrid contains –O functional groups coming from MXene, which causes an increase in electrochemical activity at the electrode surface, resulting in enhanced capacitance.http://dx.doi.org/10.1155/2024/8297902
spellingShingle Muhammad Qaiser Manzoor
Syed Irfan
null Anwar-ul-Haq
Xuyang Shi
MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles
Journal of Nanotechnology
title MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles
title_full MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles
title_fullStr MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles
title_full_unstemmed MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles
title_short MXene-Assisted Enhanced Electrochemical Performance of Doped Strontium Titanium Nanoparticles
title_sort mxene assisted enhanced electrochemical performance of doped strontium titanium nanoparticles
url http://dx.doi.org/10.1155/2024/8297902
work_keys_str_mv AT muhammadqaisermanzoor mxeneassistedenhancedelectrochemicalperformanceofdopedstrontiumtitaniumnanoparticles
AT syedirfan mxeneassistedenhancedelectrochemicalperformanceofdopedstrontiumtitaniumnanoparticles
AT nullanwarulhaq mxeneassistedenhancedelectrochemicalperformanceofdopedstrontiumtitaniumnanoparticles
AT xuyangshi mxeneassistedenhancedelectrochemicalperformanceofdopedstrontiumtitaniumnanoparticles