Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide

A water soluble branched cationic polyacrylamide (BCPAM) was synthesized using solution polymerization. The polymerization was initiated using potassium diperiodatocuprate, K5[Cu(HIO6)2](Cu(III)), initiating the self-condensing vinyl copolymerization of acrylamide and acryloxyethyltrimethyl ammonium...

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Main Authors: Weimin Sun, Guangcheng Zhang, Ling Pan, Helin Li, Aihua Shi
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2013/397027
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author Weimin Sun
Guangcheng Zhang
Ling Pan
Helin Li
Aihua Shi
author_facet Weimin Sun
Guangcheng Zhang
Ling Pan
Helin Li
Aihua Shi
author_sort Weimin Sun
collection DOAJ
description A water soluble branched cationic polyacrylamide (BCPAM) was synthesized using solution polymerization. The polymerization was initiated using potassium diperiodatocuprate, K5[Cu(HIO6)2](Cu(III)), initiating the self-condensing vinyl copolymerization of acrylamide and acryloxyethyltrimethyl ammonium chloride (DAC) monomer. The resulting copolymer was characterized by the use of Fourier-transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy. Its flocculation properties were evaluated with standard jar tests of sewage. The effects of initiator concentration, monomer concentration, reaction temperature, and the mass ratio of monomers on intrinsic viscosity and flocculation properties of the product were determined using single-factor experiments and orthogonal experiment.
format Article
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institution Kabale University
issn 1687-9422
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language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-64d96f3c21ae480d9435158fe16d32f82025-02-03T05:58:44ZengWileyInternational Journal of Polymer Science1687-94221687-94302013-01-01201310.1155/2013/397027397027Synthesis, Characterization, and Flocculation Properties of Branched Cationic PolyacrylamideWeimin Sun0Guangcheng Zhang1Ling Pan2Helin Li3Aihua Shi4Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, ChinaDepartment of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, ChinaDepartment of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, ChinaDepartment of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, ChinaDepartment of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi’an 710072, ChinaA water soluble branched cationic polyacrylamide (BCPAM) was synthesized using solution polymerization. The polymerization was initiated using potassium diperiodatocuprate, K5[Cu(HIO6)2](Cu(III)), initiating the self-condensing vinyl copolymerization of acrylamide and acryloxyethyltrimethyl ammonium chloride (DAC) monomer. The resulting copolymer was characterized by the use of Fourier-transform infrared (FTIR) spectroscopy and nuclear magnetic resonance (NMR) spectroscopy. Its flocculation properties were evaluated with standard jar tests of sewage. The effects of initiator concentration, monomer concentration, reaction temperature, and the mass ratio of monomers on intrinsic viscosity and flocculation properties of the product were determined using single-factor experiments and orthogonal experiment.http://dx.doi.org/10.1155/2013/397027
spellingShingle Weimin Sun
Guangcheng Zhang
Ling Pan
Helin Li
Aihua Shi
Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide
International Journal of Polymer Science
title Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide
title_full Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide
title_fullStr Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide
title_full_unstemmed Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide
title_short Synthesis, Characterization, and Flocculation Properties of Branched Cationic Polyacrylamide
title_sort synthesis characterization and flocculation properties of branched cationic polyacrylamide
url http://dx.doi.org/10.1155/2013/397027
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AT helinli synthesischaracterizationandflocculationpropertiesofbranchedcationicpolyacrylamide
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