In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperatur...
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| Format: | Article |
| Language: | English |
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Universidade Federal de Viçosa (UFV)
2024-04-01
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| Series: | The Journal of Engineering and Exact Sciences |
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| Online Access: | https://periodicos.ufv.br/jcec/article/view/18614 |
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| author | Catia Santin Zanchett Battiston Carolina Elisa Demaman Oro Aline M. Moreira Ficanha Paloma Truccolo Reato Natalia Paroul Rogério Marcos Dallago Marcelo Mignoni |
| author_facet | Catia Santin Zanchett Battiston Carolina Elisa Demaman Oro Aline M. Moreira Ficanha Paloma Truccolo Reato Natalia Paroul Rogério Marcos Dallago Marcelo Mignoni |
| author_sort | Catia Santin Zanchett Battiston |
| collection | DOAJ |
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The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion. Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications.
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| format | Article |
| id | doaj-art-646170486cd2422bb55bae981b218ab2 |
| institution | Kabale University |
| issn | 2527-1075 |
| language | English |
| publishDate | 2024-04-01 |
| publisher | Universidade Federal de Viçosa (UFV) |
| record_format | Article |
| series | The Journal of Engineering and Exact Sciences |
| spelling | doaj-art-646170486cd2422bb55bae981b218ab22025-02-02T19:53:51ZengUniversidade Federal de Viçosa (UFV)The Journal of Engineering and Exact Sciences2527-10752024-04-0110310.18540/jcecvl10iss3pp18614In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactionsCatia Santin Zanchett Battiston 0Carolina Elisa Demaman Oro1Aline M. Moreira Ficanha 2Paloma Truccolo Reato3Natalia Paroul4Rogério Marcos Dallago5Marcelo Mignoni6Instituto Federal de Educação, Ciência e Tecnologia do Rio Grande do Sul, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões, Brazil The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion. Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications. https://periodicos.ufv.br/jcec/article/view/18614Synthesis of geranylIonic SolidsEnzymatic route catalystIndustrial applications |
| spellingShingle | Catia Santin Zanchett Battiston Carolina Elisa Demaman Oro Aline M. Moreira Ficanha Paloma Truccolo Reato Natalia Paroul Rogério Marcos Dallago Marcelo Mignoni In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions The Journal of Engineering and Exact Sciences Synthesis of geranyl Ionic Solids Enzymatic route catalyst Industrial applications |
| title | In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
| title_full | In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
| title_fullStr | In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
| title_full_unstemmed | In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
| title_short | In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
| title_sort | in situ immobilization of cal b enzyme in mesoporous materials of the mcm 48 type using different ionic solids synthesis and application in esterification reactions |
| topic | Synthesis of geranyl Ionic Solids Enzymatic route catalyst Industrial applications |
| url | https://periodicos.ufv.br/jcec/article/view/18614 |
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