Squaraine Planar-Heterojunction Solar Cells

The photovoltaic performance of squaraine-based organic solar cells is investigated. Two squaraine derivatives with extraordinarily high extinction coefficients are used as electron donors in bilayer heterojunctions with fullerene C60 as electron acceptor. Due to the very strong squaraine absorption...

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Main Authors: Bin Fan, Ylenia Maniglio, Marina Simeunovic, Simon Kuster, Thomas Geiger, Roland Hany, Frank Nüesch
Format: Article
Language:English
Published: Wiley 2009-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2009/581068
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author Bin Fan
Ylenia Maniglio
Marina Simeunovic
Simon Kuster
Thomas Geiger
Roland Hany
Frank Nüesch
author_facet Bin Fan
Ylenia Maniglio
Marina Simeunovic
Simon Kuster
Thomas Geiger
Roland Hany
Frank Nüesch
author_sort Bin Fan
collection DOAJ
description The photovoltaic performance of squaraine-based organic solar cells is investigated. Two squaraine derivatives with extraordinarily high extinction coefficients are used as electron donors in bilayer heterojunctions with fullerene C60 as electron acceptor. Due to the very strong squaraine absorption band in the red spectral domain, antibatic behavior due to light filtering is observed in the photocurrent spectrum for film thicknesses of 35 nm to 40 nm. At reduced film thicknesses of 20 nm, this filtering effect at maximum absorption can be alleviated and power conversion efficiencies under simulated AM 1.5 full sun irradiation of 0.59% and 1.01% are obtained for the two squaraine derivatives, respectively. The photovoltaic properties of these cells are investigated with respect to electrode materials and chemical doping.
format Article
id doaj-art-639e538ae48547f084e669c284bdfc01
institution Kabale University
issn 1110-662X
1687-529X
language English
publishDate 2009-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-639e538ae48547f084e669c284bdfc012025-02-03T07:25:41ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2009-01-01200910.1155/2009/581068581068Squaraine Planar-Heterojunction Solar CellsBin Fan0Ylenia Maniglio1Marina Simeunovic2Simon Kuster3Thomas Geiger4Roland Hany5Frank Nüesch6Swiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandSwiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandSwiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandSwiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandSwiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandSwiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandSwiss Federal Laboratories for Materials Testing and Research, EMPA, Ueberlandstrasse 129, 8600 Dübendorf, SwitzerlandThe photovoltaic performance of squaraine-based organic solar cells is investigated. Two squaraine derivatives with extraordinarily high extinction coefficients are used as electron donors in bilayer heterojunctions with fullerene C60 as electron acceptor. Due to the very strong squaraine absorption band in the red spectral domain, antibatic behavior due to light filtering is observed in the photocurrent spectrum for film thicknesses of 35 nm to 40 nm. At reduced film thicknesses of 20 nm, this filtering effect at maximum absorption can be alleviated and power conversion efficiencies under simulated AM 1.5 full sun irradiation of 0.59% and 1.01% are obtained for the two squaraine derivatives, respectively. The photovoltaic properties of these cells are investigated with respect to electrode materials and chemical doping.http://dx.doi.org/10.1155/2009/581068
spellingShingle Bin Fan
Ylenia Maniglio
Marina Simeunovic
Simon Kuster
Thomas Geiger
Roland Hany
Frank Nüesch
Squaraine Planar-Heterojunction Solar Cells
International Journal of Photoenergy
title Squaraine Planar-Heterojunction Solar Cells
title_full Squaraine Planar-Heterojunction Solar Cells
title_fullStr Squaraine Planar-Heterojunction Solar Cells
title_full_unstemmed Squaraine Planar-Heterojunction Solar Cells
title_short Squaraine Planar-Heterojunction Solar Cells
title_sort squaraine planar heterojunction solar cells
url http://dx.doi.org/10.1155/2009/581068
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AT yleniamaniglio squaraineplanarheterojunctionsolarcells
AT marinasimeunovic squaraineplanarheterojunctionsolarcells
AT simonkuster squaraineplanarheterojunctionsolarcells
AT thomasgeiger squaraineplanarheterojunctionsolarcells
AT rolandhany squaraineplanarheterojunctionsolarcells
AT franknuesch squaraineplanarheterojunctionsolarcells