Leaching of hemimorphite in neutral solution at high temperature

The leaching behavior of hemimorphite in neutral solution (NH4 +-Cl--H2O) was investigated at high temperature (T > 100°C) under a range of experimental conditions. Thermodynamic calculations indicate that the tendency of dehydration of silica gel is significantly enhanced with the increasing tem...

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Main Authors: Zhao D.-Q., Yang S.-H., Chen Y.-M., Tang C.-B, He J., Li H.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2020-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2020/1450-53392000014Z.pdf
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author Zhao D.-Q.
Yang S.-H.
Chen Y.-M.
Tang C.-B
He J.
Li H.
author_facet Zhao D.-Q.
Yang S.-H.
Chen Y.-M.
Tang C.-B
He J.
Li H.
author_sort Zhao D.-Q.
collection DOAJ
description The leaching behavior of hemimorphite in neutral solution (NH4 +-Cl--H2O) was investigated at high temperature (T > 100°C) under a range of experimental conditions. Thermodynamic calculations indicate that the tendency of dehydration of silica gel is significantly enhanced with the increasing temperature. It was shown that the temperature, ammonium chloride concentration, or L/S ratio increased resulted in greater leaching efficiency. The following optimized leaching conditions were obtained: stirrer speed 400r/min, NH4Cl concentration 5.5M, L/S ratio 9mL/g at 160°C for 3h. Under these optimized conditions, the average leaching yield of zinc was 97.82%. The silicon was converted to quartz and remained in the residue. This process can be used to dispose willemite and hemimorphite as it solves the problem of silica gel dehydration.
format Article
id doaj-art-6399a412e9894f79854b390c5069770a
institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2020-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-6399a412e9894f79854b390c5069770a2025-02-02T06:57:43ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752020-01-0156220320810.2298/JMMB191016014Z1450-53392000014ZLeaching of hemimorphite in neutral solution at high temperatureZhao D.-Q.0Yang S.-H.1Chen Y.-M.2Tang C.-B3He J.4Li H.5School of Metallurgy and Environment, Central South University, National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Changsha, ChinaSchool of Metallurgy and Environment, Central South University, National Engineering Laboratory for High Efficiency Recovery of Refractory Nonferrous Metals, Changsha, ChinaThe leaching behavior of hemimorphite in neutral solution (NH4 +-Cl--H2O) was investigated at high temperature (T > 100°C) under a range of experimental conditions. Thermodynamic calculations indicate that the tendency of dehydration of silica gel is significantly enhanced with the increasing temperature. It was shown that the temperature, ammonium chloride concentration, or L/S ratio increased resulted in greater leaching efficiency. The following optimized leaching conditions were obtained: stirrer speed 400r/min, NH4Cl concentration 5.5M, L/S ratio 9mL/g at 160°C for 3h. Under these optimized conditions, the average leaching yield of zinc was 97.82%. The silicon was converted to quartz and remained in the residue. This process can be used to dispose willemite and hemimorphite as it solves the problem of silica gel dehydration.http://www.doiserbia.nb.rs/img/doi/1450-5339/2020/1450-53392000014Z.pdfpressure leachingammonium chloridehemimorphitesilica gel
spellingShingle Zhao D.-Q.
Yang S.-H.
Chen Y.-M.
Tang C.-B
He J.
Li H.
Leaching of hemimorphite in neutral solution at high temperature
Journal of Mining and Metallurgy. Section B: Metallurgy
pressure leaching
ammonium chloride
hemimorphite
silica gel
title Leaching of hemimorphite in neutral solution at high temperature
title_full Leaching of hemimorphite in neutral solution at high temperature
title_fullStr Leaching of hemimorphite in neutral solution at high temperature
title_full_unstemmed Leaching of hemimorphite in neutral solution at high temperature
title_short Leaching of hemimorphite in neutral solution at high temperature
title_sort leaching of hemimorphite in neutral solution at high temperature
topic pressure leaching
ammonium chloride
hemimorphite
silica gel
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2020/1450-53392000014Z.pdf
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AT yangsh leachingofhemimorphiteinneutralsolutionathightemperature
AT chenym leachingofhemimorphiteinneutralsolutionathightemperature
AT tangcb leachingofhemimorphiteinneutralsolutionathightemperature
AT hej leachingofhemimorphiteinneutralsolutionathightemperature
AT lih leachingofhemimorphiteinneutralsolutionathightemperature