Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites

Self-healing materials are beginning to be considered for applications in the field of structural materials. For this reason, in addition to self-healing efficiency, also mechanical properties such as tensile and compressive properties are beginning to become more and more important for this kind of...

Full description

Saved in:
Bibliographic Details
Main Authors: Liberata Guadagno, Marialuigia Raimondo, Umberto Vietri, Carlo Naddeo, Anja Stojanovic, Andrea Sorrentino, Wolfgang H. Binder
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Aerospace Engineering
Online Access:http://dx.doi.org/10.1155/2016/7817962
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832568215848353792
author Liberata Guadagno
Marialuigia Raimondo
Umberto Vietri
Carlo Naddeo
Anja Stojanovic
Andrea Sorrentino
Wolfgang H. Binder
author_facet Liberata Guadagno
Marialuigia Raimondo
Umberto Vietri
Carlo Naddeo
Anja Stojanovic
Andrea Sorrentino
Wolfgang H. Binder
author_sort Liberata Guadagno
collection DOAJ
description Self-healing materials are beginning to be considered for applications in the field of structural materials. For this reason, in addition to self-healing efficiency, also mechanical properties such as tensile and compressive properties are beginning to become more and more important for this kind of materials. In this paper, three different systems based on epoxy-resins/ethylidene-norbornene (ENB)/Hoveyda-Grubbs 1st-generation (HG1) catalyst are investigated in terms of mechanical properties and healing efficiency. The experimental results show that the mechanical properties of the self-healing systems are mainly determined by the chemical nature of the epoxy matrix. In particular, the replacement of a conventional flexibilizer (Heloxy 71) with a reactive diluent (1,4-butanediol diglycidyl ether) allows obtaining self-healing materials with better mechanical properties and higher thermal stability. An increase in the curing temperature causes an increase in the elastic modulus and a slight reduction of the healing efficiency. These results can constitute the basis to design systems with high regenerative ability and appropriate mechanical performance.
format Article
id doaj-art-634f87e4601c4ab39e5af041eb501dd4
institution Kabale University
issn 1687-5966
1687-5974
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series International Journal of Aerospace Engineering
spelling doaj-art-634f87e4601c4ab39e5af041eb501dd42025-02-03T00:59:28ZengWileyInternational Journal of Aerospace Engineering1687-59661687-59742016-01-01201610.1155/2016/78179627817962Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing CompositesLiberata Guadagno0Marialuigia Raimondo1Umberto Vietri2Carlo Naddeo3Anja Stojanovic4Andrea Sorrentino5Wolfgang H. Binder6Department of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132-84084 Fisciano, ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132-84084 Fisciano, ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132-84084 Fisciano, ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132-84084 Fisciano, ItalyFaculty of Natural Sciences II, Institute of Chemistry, Chair of Macromolecular Science, Martin Luther University of Halle-Wittenberg, von-Danckelmann-Platz 4, 06120 Halle (Saale), GermanyInstitute for Polymers Composites and Biomaterials (IPCB), CNR, Piazzale Enrico Fermi 1, 80055 Portici, ItalyFaculty of Natural Sciences II, Institute of Chemistry, Chair of Macromolecular Science, Martin Luther University of Halle-Wittenberg, von-Danckelmann-Platz 4, 06120 Halle (Saale), GermanySelf-healing materials are beginning to be considered for applications in the field of structural materials. For this reason, in addition to self-healing efficiency, also mechanical properties such as tensile and compressive properties are beginning to become more and more important for this kind of materials. In this paper, three different systems based on epoxy-resins/ethylidene-norbornene (ENB)/Hoveyda-Grubbs 1st-generation (HG1) catalyst are investigated in terms of mechanical properties and healing efficiency. The experimental results show that the mechanical properties of the self-healing systems are mainly determined by the chemical nature of the epoxy matrix. In particular, the replacement of a conventional flexibilizer (Heloxy 71) with a reactive diluent (1,4-butanediol diglycidyl ether) allows obtaining self-healing materials with better mechanical properties and higher thermal stability. An increase in the curing temperature causes an increase in the elastic modulus and a slight reduction of the healing efficiency. These results can constitute the basis to design systems with high regenerative ability and appropriate mechanical performance.http://dx.doi.org/10.1155/2016/7817962
spellingShingle Liberata Guadagno
Marialuigia Raimondo
Umberto Vietri
Carlo Naddeo
Anja Stojanovic
Andrea Sorrentino
Wolfgang H. Binder
Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites
International Journal of Aerospace Engineering
title Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites
title_full Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites
title_fullStr Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites
title_full_unstemmed Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites
title_short Evaluation of the Mechanical Properties of Microcapsule-Based Self-Healing Composites
title_sort evaluation of the mechanical properties of microcapsule based self healing composites
url http://dx.doi.org/10.1155/2016/7817962
work_keys_str_mv AT liberataguadagno evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites
AT marialuigiaraimondo evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites
AT umbertovietri evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites
AT carlonaddeo evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites
AT anjastojanovic evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites
AT andreasorrentino evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites
AT wolfganghbinder evaluationofthemechanicalpropertiesofmicrocapsulebasedselfhealingcomposites