Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries

The increasing global population and, thus, energy demand have made research into renewable energy sources more critical. Lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) have been recognized as the most promising technologies for storing energy and effectively addressing this demand. Ca...

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Main Authors: Koorosh Nikgoftar, Anil Kumar Madikere Raghunatha Reddy, Mogalahalli Venkatashamy Reddy, Karim Zaghib
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Batteries
Subjects:
Online Access:https://www.mdpi.com/2313-0105/11/4/123
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author Koorosh Nikgoftar
Anil Kumar Madikere Raghunatha Reddy
Mogalahalli Venkatashamy Reddy
Karim Zaghib
author_facet Koorosh Nikgoftar
Anil Kumar Madikere Raghunatha Reddy
Mogalahalli Venkatashamy Reddy
Karim Zaghib
author_sort Koorosh Nikgoftar
collection DOAJ
description The increasing global population and, thus, energy demand have made research into renewable energy sources more critical. Lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) have been recognized as the most promising technologies for storing energy and effectively addressing this demand. Carbonaceous materials are the most widespread anode material due to their fascinating features, such as high theoretical capacity, high electrical conductivity, and excellent structural stability. Additionally, these materials’ abundance, cost-effectiveness, and environmental friendliness have emphasized the need for further investigation and development. Among these carbon-based materials, graphite (both artificial and natural) stands out as the most ubiquitous anode material due to its layered crystal structure, high mechanical strength, long cycle life, and excellent safety profile, making it ideal for intercalation with lithium and sodium. In recent years, extensive research has been conducted to enhance the efficiency of anodes and, ultimately, the overall performance of batteries. In this review, the role of carbonaceous materials in anodes for lithium-ion and sodium-ion batteries was comprehensively investigated, focusing on advancements in synthesizing and optimizing artificial graphite. Furthermore, the intercalation mechanism and the factors influencing the electrochemical properties of both LIBs and SIBs were extensively discussed. This work also provides a holistic perspective on the differences between these two types of batteries, highlighting their cost, safety applications, and future potential advancement.
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publisher MDPI AG
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series Batteries
spelling doaj-art-6124d59e7e3e4eb1a22f86c09d918dba2025-08-20T02:24:42ZengMDPI AGBatteries2313-01052025-03-0111412310.3390/batteries11040123Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion BatteriesKoorosh Nikgoftar0Anil Kumar Madikere Raghunatha Reddy1Mogalahalli Venkatashamy Reddy2Karim Zaghib3Department of Chemical and Materials Engineering, Concordia University, 1455 De Maisonneuve Blvd. West, Montreal, QC H3G 1M8, CanadaDepartment of Chemical and Materials Engineering, Concordia University, 1455 De Maisonneuve Blvd. West, Montreal, QC H3G 1M8, CanadaNouveau Monde Graphite (NMG), Saint-Michel-des-Saints, QC J0K 3B0, CanadaDepartment of Chemical and Materials Engineering, Concordia University, 1455 De Maisonneuve Blvd. West, Montreal, QC H3G 1M8, CanadaThe increasing global population and, thus, energy demand have made research into renewable energy sources more critical. Lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) have been recognized as the most promising technologies for storing energy and effectively addressing this demand. Carbonaceous materials are the most widespread anode material due to their fascinating features, such as high theoretical capacity, high electrical conductivity, and excellent structural stability. Additionally, these materials’ abundance, cost-effectiveness, and environmental friendliness have emphasized the need for further investigation and development. Among these carbon-based materials, graphite (both artificial and natural) stands out as the most ubiquitous anode material due to its layered crystal structure, high mechanical strength, long cycle life, and excellent safety profile, making it ideal for intercalation with lithium and sodium. In recent years, extensive research has been conducted to enhance the efficiency of anodes and, ultimately, the overall performance of batteries. In this review, the role of carbonaceous materials in anodes for lithium-ion and sodium-ion batteries was comprehensively investigated, focusing on advancements in synthesizing and optimizing artificial graphite. Furthermore, the intercalation mechanism and the factors influencing the electrochemical properties of both LIBs and SIBs were extensively discussed. This work also provides a holistic perspective on the differences between these two types of batteries, highlighting their cost, safety applications, and future potential advancement.https://www.mdpi.com/2313-0105/11/4/123lithium-ion batteriessodium-ion batteriesanodenatural graphiteartificial graphitehard/soft carbon
spellingShingle Koorosh Nikgoftar
Anil Kumar Madikere Raghunatha Reddy
Mogalahalli Venkatashamy Reddy
Karim Zaghib
Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
Batteries
lithium-ion batteries
sodium-ion batteries
anode
natural graphite
artificial graphite
hard/soft carbon
title Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
title_full Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
title_fullStr Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
title_full_unstemmed Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
title_short Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
title_sort carbonaceous materials as anodes for lithium ion and sodium ion batteries
topic lithium-ion batteries
sodium-ion batteries
anode
natural graphite
artificial graphite
hard/soft carbon
url https://www.mdpi.com/2313-0105/11/4/123
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AT anilkumarmadikereraghunathareddy carbonaceousmaterialsasanodesforlithiumionandsodiumionbatteries
AT mogalahallivenkatashamyreddy carbonaceousmaterialsasanodesforlithiumionandsodiumionbatteries
AT karimzaghib carbonaceousmaterialsasanodesforlithiumionandsodiumionbatteries