Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application
Chicken feather protein (CFP), and lecithin (L), Tween 80 (T), and DOSS (D) surfactant systems were loaded onto halloysite nanotubes (HNTs), a natural clay aluminosilicate product to form particulate dispersants at different surfactant concentrations and characterized by Fourier Transform Infrared s...
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Elsevier
2025-01-01
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| Series: | Heliyon |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844025003317 |
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| author | Yaw Kwakye Adofo Emmanuel Nyankson Benjamin Agyei-Tuffour Selassie Gbogbo Christian Amoako Joseph Arko Morgan Gloria Pokuaa Manu Grace Karikari Arkorful |
| author_facet | Yaw Kwakye Adofo Emmanuel Nyankson Benjamin Agyei-Tuffour Selassie Gbogbo Christian Amoako Joseph Arko Morgan Gloria Pokuaa Manu Grace Karikari Arkorful |
| author_sort | Yaw Kwakye Adofo |
| collection | DOAJ |
| description | Chicken feather protein (CFP), and lecithin (L), Tween 80 (T), and DOSS (D) surfactant systems were loaded onto halloysite nanotubes (HNTs), a natural clay aluminosilicate product to form particulate dispersants at different surfactant concentrations and characterized by Fourier Transform Infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy coupled with EDS. For 24 wt% surfactants concentrations loaded HNTs; 100 wt%CFP-HNTs, 60 wt%CFP- 40 wt%L-HNTs, 20 wt%CFP- 80 wt%T-HNTs, 50 wt%CFP- 25 wt%T-25 wt%L-HNTs and 25 wt %CFP- 25 wt%T-50 wt%D-HNTs showed good interfacial tension lowering abilities by recording 6.39, 2.82, 2.43, 1.68, and 1.55 mN/m at 60s respectively. The CFP-based surfactant-HNTs dispersants formed very stable o/w emulsions against droplet coalescence and showed an increase in interfacial viscosity which contributed to the stability of their respective o/w emulsions. In this study, the US EPA's baffled flask test was deployed to probe the prospects of the CFP-based surfactants-HNTs dispersants in crude oil dispersion at different surfactant concentrations. 100 wt%CFP-HNTs, 60 wt %CFP- 40 wt %L-HNTs, 20 wt %CFP- 80 wt %T-HNTs, 50 wt %CFP- 25 wt%T-25 wt%L-HNTs and 25 wt%CFP- 25 wt%T-50 wt%D-HNTs recorded dispersion effectiveness of 33.9, 74.8, 65.4, 78.6 and 88.2 vol% respectively at 24 wt% surfactant concentration. It can be deduced that an increase in the surfactant concentrations loaded onto HNTs improved the dispersion effectiveness of the produced particulate dispersants. Largely, the 24 wt% CFP-based surfactant-HNTs dispersants showed considerable promise in crude oil dispersion in seawater. |
| format | Article |
| id | doaj-art-601de4c96a6e4545b3c9e79dd6218bcd |
| institution | Kabale University |
| issn | 2405-8440 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Elsevier |
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| series | Heliyon |
| spelling | doaj-art-601de4c96a6e4545b3c9e79dd6218bcd2025-02-02T05:28:38ZengElsevierHeliyon2405-84402025-01-01112e41951Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion applicationYaw Kwakye Adofo0Emmanuel Nyankson1Benjamin Agyei-Tuffour2Selassie Gbogbo3Christian Amoako4Joseph Arko Morgan5Gloria Pokuaa Manu6Grace Karikari Arkorful7Material Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaCorresponding author.; Material Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaMaterial Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaMaterial Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaMaterial Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaMaterial Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaMaterial Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaMaterial Science and Engineering Department, School of Engineering Sciences, University of Ghana, Legon-Accra, GhanaChicken feather protein (CFP), and lecithin (L), Tween 80 (T), and DOSS (D) surfactant systems were loaded onto halloysite nanotubes (HNTs), a natural clay aluminosilicate product to form particulate dispersants at different surfactant concentrations and characterized by Fourier Transform Infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy coupled with EDS. For 24 wt% surfactants concentrations loaded HNTs; 100 wt%CFP-HNTs, 60 wt%CFP- 40 wt%L-HNTs, 20 wt%CFP- 80 wt%T-HNTs, 50 wt%CFP- 25 wt%T-25 wt%L-HNTs and 25 wt %CFP- 25 wt%T-50 wt%D-HNTs showed good interfacial tension lowering abilities by recording 6.39, 2.82, 2.43, 1.68, and 1.55 mN/m at 60s respectively. The CFP-based surfactant-HNTs dispersants formed very stable o/w emulsions against droplet coalescence and showed an increase in interfacial viscosity which contributed to the stability of their respective o/w emulsions. In this study, the US EPA's baffled flask test was deployed to probe the prospects of the CFP-based surfactants-HNTs dispersants in crude oil dispersion at different surfactant concentrations. 100 wt%CFP-HNTs, 60 wt %CFP- 40 wt %L-HNTs, 20 wt %CFP- 80 wt %T-HNTs, 50 wt %CFP- 25 wt%T-25 wt%L-HNTs and 25 wt%CFP- 25 wt%T-50 wt%D-HNTs recorded dispersion effectiveness of 33.9, 74.8, 65.4, 78.6 and 88.2 vol% respectively at 24 wt% surfactant concentration. It can be deduced that an increase in the surfactant concentrations loaded onto HNTs improved the dispersion effectiveness of the produced particulate dispersants. Largely, the 24 wt% CFP-based surfactant-HNTs dispersants showed considerable promise in crude oil dispersion in seawater.http://www.sciencedirect.com/science/article/pii/S2405844025003317Halloysite nanotubesChicken feather proteinParticulate dispersantsCrude oil dispersionSynergistic interaction |
| spellingShingle | Yaw Kwakye Adofo Emmanuel Nyankson Benjamin Agyei-Tuffour Selassie Gbogbo Christian Amoako Joseph Arko Morgan Gloria Pokuaa Manu Grace Karikari Arkorful Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application Heliyon Halloysite nanotubes Chicken feather protein Particulate dispersants Crude oil dispersion Synergistic interaction |
| title | Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application |
| title_full | Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application |
| title_fullStr | Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application |
| title_full_unstemmed | Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application |
| title_short | Halloysite nanotubes as delivery mechanism for feather protein-based multi-surfactant systems in crude oil dispersion application |
| title_sort | halloysite nanotubes as delivery mechanism for feather protein based multi surfactant systems in crude oil dispersion application |
| topic | Halloysite nanotubes Chicken feather protein Particulate dispersants Crude oil dispersion Synergistic interaction |
| url | http://www.sciencedirect.com/science/article/pii/S2405844025003317 |
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