Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials
Abstract The use of increasingly advanced energetic materials (EMs) in various branches of industry and military sectors increases the appropriate requirements for EMs, including: their durability, safety of use, chemical and high-energetic properties. Additionally, the impact of the products of the...
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| Format: | Article |
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Nature Portfolio
2024-06-01
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| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-024-64974-w |
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| author | Mateusz Polis Agnieszka Stolarczyk Konrad Szydło Magdalena Fabin Mateusz Pytlik Barbara Lisiecka Tomasz Jarosz |
| author_facet | Mateusz Polis Agnieszka Stolarczyk Konrad Szydło Magdalena Fabin Mateusz Pytlik Barbara Lisiecka Tomasz Jarosz |
| author_sort | Mateusz Polis |
| collection | DOAJ |
| description | Abstract The use of increasingly advanced energetic materials (EMs) in various branches of industry and military sectors increases the appropriate requirements for EMs, including: their durability, safety of use, chemical and high-energetic properties. Additionally, the impact of the products of the explosion of EMs on the natural environment is also crucial. Therefore, on-site mixture (OSM) energetic materials containing concentrated hydrogen peroxide (OSM-type energetic materials) are becoming increasingly popular. This is an extremely interesting group of materials that contains in excess of 50 wt.% hydrogen peroxide (HP) and not containing toxic compounds, and therefore is environmentally friendly. The main objective of the study was to investigate the various compositions of OSM-type energetic materials in terms of the evolution over time of their energetic properties (including the “raw” energetic material strength and the ability to sustain the propagation of a detonation wave) and the volume of the post-detonation gases. The obtained results show that the decomposition of hydrogen peroxide strongly affects the detonation parameters of OSM-type energetic material and the decomposition time of HP. In addition, it has been proven that rate of decomposition of HP significantly affects the detonation parameters of OSM-type energetic materials. It was also found that the concentration of NO $$_{\hbox {x}}$$ x is low and decreases dramatically with the decomposition of hydrogen peroxide, but at the same time the concentration of carbon oxides increases. |
| format | Article |
| id | doaj-art-6011240a80e34382be000dbbc6458fd9 |
| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2024-06-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj-art-6011240a80e34382be000dbbc6458fd92025-01-26T12:35:19ZengNature PortfolioScientific Reports2045-23222024-06-0114111510.1038/s41598-024-64974-wComprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materialsMateusz Polis0Agnieszka Stolarczyk1Konrad Szydło2Magdalena Fabin3Mateusz Pytlik4Barbara Lisiecka5Tomasz Jarosz6Department of Physical Chemistry and Technology of Polymers, Silesian University of TechnologyDepartment of Physical Chemistry and Technology of Polymers, Silesian University of TechnologyDepartment of Physical Chemistry and Technology of Polymers, Silesian University of TechnologyDepartment of Physical Chemistry and Technology of Polymers, Silesian University of TechnologyNational Research Institute, Conformity Assessment Body, Central Mining InstituteExplosive Techniques Research Group, Łukasiewicz Research Network - Institute of Industrial Organic ChemistryDepartment of Physical Chemistry and Technology of Polymers, Silesian University of TechnologyAbstract The use of increasingly advanced energetic materials (EMs) in various branches of industry and military sectors increases the appropriate requirements for EMs, including: their durability, safety of use, chemical and high-energetic properties. Additionally, the impact of the products of the explosion of EMs on the natural environment is also crucial. Therefore, on-site mixture (OSM) energetic materials containing concentrated hydrogen peroxide (OSM-type energetic materials) are becoming increasingly popular. This is an extremely interesting group of materials that contains in excess of 50 wt.% hydrogen peroxide (HP) and not containing toxic compounds, and therefore is environmentally friendly. The main objective of the study was to investigate the various compositions of OSM-type energetic materials in terms of the evolution over time of their energetic properties (including the “raw” energetic material strength and the ability to sustain the propagation of a detonation wave) and the volume of the post-detonation gases. The obtained results show that the decomposition of hydrogen peroxide strongly affects the detonation parameters of OSM-type energetic material and the decomposition time of HP. In addition, it has been proven that rate of decomposition of HP significantly affects the detonation parameters of OSM-type energetic materials. It was also found that the concentration of NO $$_{\hbox {x}}$$ x is low and decreases dramatically with the decomposition of hydrogen peroxide, but at the same time the concentration of carbon oxides increases.https://doi.org/10.1038/s41598-024-64974-w |
| spellingShingle | Mateusz Polis Agnieszka Stolarczyk Konrad Szydło Magdalena Fabin Mateusz Pytlik Barbara Lisiecka Tomasz Jarosz Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials Scientific Reports |
| title | Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials |
| title_full | Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials |
| title_fullStr | Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials |
| title_full_unstemmed | Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials |
| title_short | Comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of OSM-type energetic materials |
| title_sort | comprehensive study on impact of hydrogen peroxide decomposition on the crucial parameters of osm type energetic materials |
| url | https://doi.org/10.1038/s41598-024-64974-w |
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