Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure

Zinc oxide (ZnO)/titanium dioxide (TiO2) nanorods have been synthesized via a hydrothermal method for ZnO nanorods and an electron-beam deposition for TiO2 nanorods. This work examined the effect of annealing ZnO seed layer on the photocatalytic activity of the ZnO/TiO2 nanorods which was determined...

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Main Authors: Woo-Young Kim, Soon-Wook Kim, Dae-Hwang Yoo, Eui Jung Kim, Sung Hong Hahn
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/130541
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author Woo-Young Kim
Soon-Wook Kim
Dae-Hwang Yoo
Eui Jung Kim
Sung Hong Hahn
author_facet Woo-Young Kim
Soon-Wook Kim
Dae-Hwang Yoo
Eui Jung Kim
Sung Hong Hahn
author_sort Woo-Young Kim
collection DOAJ
description Zinc oxide (ZnO)/titanium dioxide (TiO2) nanorods have been synthesized via a hydrothermal method for ZnO nanorods and an electron-beam deposition for TiO2 nanorods. This work examined the effect of annealing ZnO seed layer on the photocatalytic activity of the ZnO/TiO2 nanorods which was determined from photodecomposition of methylene blue under UV irradiation. The photocatalytic activity of the ZnO/TiO2 nanorods was improved with increasing annealing temperature of the seed layer from 300°C to 500°C. Annealing the seed layer at 500°C showed the best photocatalytic activity resulting from high UV absorption ability, a large surface area with flower structure and copious oxygen defects which promote separation of electron-hole pairs reducing electron recombination. The prepared nanorods were characterized by field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), photoluminescence (PL), and UV-visible spectroscopy.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-5e31f1c97c49485bb580bac0ed6c5abf2025-02-03T06:00:33ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/130541130541Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 NanostructureWoo-Young Kim0Soon-Wook Kim1Dae-Hwang Yoo2Eui Jung Kim3Sung Hong Hahn4Department of Physics, University of Ulsan, Ulsan 680-749, Republic of KoreaDepartment of Physics, University of Ulsan, Ulsan 680-749, Republic of KoreaDepartment of Physics, University of Ulsan, Ulsan 680-749, Republic of KoreaDepartment of Chemical Engineering, University of Ulsan, Ulsan 680-749, Republic of KoreaDepartment of Physics, University of Ulsan, Ulsan 680-749, Republic of KoreaZinc oxide (ZnO)/titanium dioxide (TiO2) nanorods have been synthesized via a hydrothermal method for ZnO nanorods and an electron-beam deposition for TiO2 nanorods. This work examined the effect of annealing ZnO seed layer on the photocatalytic activity of the ZnO/TiO2 nanorods which was determined from photodecomposition of methylene blue under UV irradiation. The photocatalytic activity of the ZnO/TiO2 nanorods was improved with increasing annealing temperature of the seed layer from 300°C to 500°C. Annealing the seed layer at 500°C showed the best photocatalytic activity resulting from high UV absorption ability, a large surface area with flower structure and copious oxygen defects which promote separation of electron-hole pairs reducing electron recombination. The prepared nanorods were characterized by field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), photoluminescence (PL), and UV-visible spectroscopy.http://dx.doi.org/10.1155/2013/130541
spellingShingle Woo-Young Kim
Soon-Wook Kim
Dae-Hwang Yoo
Eui Jung Kim
Sung Hong Hahn
Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure
International Journal of Photoenergy
title Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure
title_full Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure
title_fullStr Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure
title_full_unstemmed Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure
title_short Annealing Effect of ZnO Seed Layer on Enhancing Photocatalytic Activity of ZnO/TiO2 Nanostructure
title_sort annealing effect of zno seed layer on enhancing photocatalytic activity of zno tio2 nanostructure
url http://dx.doi.org/10.1155/2013/130541
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AT daehwangyoo annealingeffectofznoseedlayeronenhancingphotocatalyticactivityofznotio2nanostructure
AT euijungkim annealingeffectofznoseedlayeronenhancingphotocatalyticactivityofznotio2nanostructure
AT sunghonghahn annealingeffectofznoseedlayeronenhancingphotocatalyticactivityofznotio2nanostructure