Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation

Ozonation is one of the most effective and efficient advanced oxidation processes (AOPs) and has shown great potential in the treatment of industrial effluent and wastewater. In the present work, the ozone-Fenton process for % COD and color removal together with electrical energy per order (EE/O) de...

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Main Authors: Perumal Asaithambi, Mamuye Busier Yesuf, Seifu Kebede Debela, Rajendran Govindarajan, N. M. Hariharan, Esayas Alemayehu
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:International Journal of Chemical Engineering
Online Access:http://dx.doi.org/10.1155/2022/5006911
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author Perumal Asaithambi
Mamuye Busier Yesuf
Seifu Kebede Debela
Rajendran Govindarajan
N. M. Hariharan
Esayas Alemayehu
author_facet Perumal Asaithambi
Mamuye Busier Yesuf
Seifu Kebede Debela
Rajendran Govindarajan
N. M. Hariharan
Esayas Alemayehu
author_sort Perumal Asaithambi
collection DOAJ
description Ozonation is one of the most effective and efficient advanced oxidation processes (AOPs) and has shown great potential in the treatment of industrial effluent and wastewater. In the present work, the ozone-Fenton process for % COD and color removal together with electrical energy per order (EE/O) determination for distillery industrial wastewater (DIW) was established. The process was developed by combining the ozone (O3) with the Fenton (Fe2+/H2O2) process. The ozone-Fenton (O3/Fe2+/H2O2) was compared with other treatment processes such as O3, Fe2+, H2O2, O3/Fe2+, O3/H2O2, and Fe2+/H2O2 for EE/O together with % COD and color removal efficiency for DIW. The removal of color at 100% and chemical oxygen demand (COD) of 96.875% were achieved with a minimum of EE/O of 0.5315 kWh/m3 using the O3/Fe2+/H2O2 process by operating at optimum conditions. The % COD and color values obtained using O3/Fe2+/H2O2 were significantly higher than those obtained using O3, Fe2+, H2O2, O3/Fe2+, O3/H2O2, and Fe2+/H2O2 processes. The % color, % COD removal, and its associated EE/O were evaluated by varying Fe2+, H2O2, O3 inlet and COD concentration, and initial wastewater pH using the O3/Fe2+/H2O2 process. The synergy effect of the O3 and Fe2+/H2O2 processes was evaluated and reported. Our experimental findings suggest that combining O3 with the Fe2+/H2O2 process could effectively treat industrial effluent and wastewater.
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spelling doaj-art-5e2da90c96bd4b49b9ab4bea5a84c2362025-02-03T05:53:40ZengWileyInternational Journal of Chemical Engineering1687-80782022-01-01202210.1155/2022/5006911Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order EvaluationPerumal Asaithambi0Mamuye Busier Yesuf1Seifu Kebede Debela2Rajendran Govindarajan3N. M. Hariharan4Esayas Alemayehu5Faculty of Civil and Environmental EngineeringFaculty of Civil and Environmental EngineeringFaculty of Civil and Environmental EngineeringDepartment of Chemical EngineeringDepartment of BiotechnologyFaculty of Civil and Environmental EngineeringOzonation is one of the most effective and efficient advanced oxidation processes (AOPs) and has shown great potential in the treatment of industrial effluent and wastewater. In the present work, the ozone-Fenton process for % COD and color removal together with electrical energy per order (EE/O) determination for distillery industrial wastewater (DIW) was established. The process was developed by combining the ozone (O3) with the Fenton (Fe2+/H2O2) process. The ozone-Fenton (O3/Fe2+/H2O2) was compared with other treatment processes such as O3, Fe2+, H2O2, O3/Fe2+, O3/H2O2, and Fe2+/H2O2 for EE/O together with % COD and color removal efficiency for DIW. The removal of color at 100% and chemical oxygen demand (COD) of 96.875% were achieved with a minimum of EE/O of 0.5315 kWh/m3 using the O3/Fe2+/H2O2 process by operating at optimum conditions. The % COD and color values obtained using O3/Fe2+/H2O2 were significantly higher than those obtained using O3, Fe2+, H2O2, O3/Fe2+, O3/H2O2, and Fe2+/H2O2 processes. The % color, % COD removal, and its associated EE/O were evaluated by varying Fe2+, H2O2, O3 inlet and COD concentration, and initial wastewater pH using the O3/Fe2+/H2O2 process. The synergy effect of the O3 and Fe2+/H2O2 processes was evaluated and reported. Our experimental findings suggest that combining O3 with the Fe2+/H2O2 process could effectively treat industrial effluent and wastewater.http://dx.doi.org/10.1155/2022/5006911
spellingShingle Perumal Asaithambi
Mamuye Busier Yesuf
Seifu Kebede Debela
Rajendran Govindarajan
N. M. Hariharan
Esayas Alemayehu
Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
International Journal of Chemical Engineering
title Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
title_full Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
title_fullStr Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
title_full_unstemmed Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
title_short Treatment of Distillery Industrial Wastewater Using Ozone Assisted Fenton’s Process: Color and Chemical Oxygen Demand Removal with Electrical Energy per Order Evaluation
title_sort treatment of distillery industrial wastewater using ozone assisted fenton s process color and chemical oxygen demand removal with electrical energy per order evaluation
url http://dx.doi.org/10.1155/2022/5006911
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