Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride
The primary objective of the present study is to evaluate the optimization conditions such as kinetic and equilibrium isotherm models involved in the removal of Ni(II) from the aqueous solutions by Trichoderma viride. The biosorbent was characterized by FTIR and SEM. The optimum biosorption conditio...
Saved in:
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Wiley
2013-01-01
|
Series: | Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2013/716098 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
_version_ | 1832563911884275712 |
---|---|
author | P. Sujatha V. Kalarani B. Naresh Kumar |
author_facet | P. Sujatha V. Kalarani B. Naresh Kumar |
author_sort | P. Sujatha |
collection | DOAJ |
description | The primary objective of the present study is to evaluate the optimization conditions such as kinetic and equilibrium isotherm models involved in the removal of Ni(II) from the aqueous solutions by Trichoderma viride. The biosorbent was characterized by FTIR and SEM. The optimum biosorption conditions were determined as a function of pH, biomass dosage, contact time, initial metal ion concentration, and temperature. The maximum Ni(II) biosorption was obtained at pH 4.5. The equilibrium data were better fit by the Langmuir isotherm model than by the Freundlich isotherm. The kinetic studies indicate that the biosorption process of the metal ion Ni(II) has followed well the pseudo-second-order model. The sum of the square errors (SSE) and chi-square (χ2) tests were also carried out to find the best fit kinetic model and adsorption isotherm. The maximum biosorption capacity (qm) of T. viride biomass was found to be 47.6 mg/g for Ni(II) ion. Therefore, it can be concluded that T. viride biomass was effective and low-cost potential adsorbent to remove the toxic metal Ni(II) from aqueous solutions. The recovery process of Ni(II) from T. viride biomass was found to be higher than 98% by using 0.25 M HNO3. Besides the application of removal of toxic metal Ni(II) from aqueous solutions, the biosorbent T. viride can be reused for five consecutive sorption-desorption cycles was determined. |
format | Article |
id | doaj-art-5df60b88bad94658a0033bc97d5d66af |
institution | Kabale University |
issn | 2090-9063 2090-9071 |
language | English |
publishDate | 2013-01-01 |
publisher | Wiley |
record_format | Article |
series | Journal of Chemistry |
spelling | doaj-art-5df60b88bad94658a0033bc97d5d66af2025-02-03T01:12:17ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/716098716098Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma virideP. Sujatha0V. Kalarani1B. Naresh Kumar2Department of Biotechnology, Sri Padmavati Mahila Visvavidyalayam (Women’s University), Andhara Pradesh, Tirupati 517502, IndiaDepartment of Biotechnology, Sri Padmavati Mahila Visvavidyalayam (Women’s University), Andhara Pradesh, Tirupati 517502, IndiaFood and Water Division, Vimta Life Sciences, Hyderabad 500078, IndiaThe primary objective of the present study is to evaluate the optimization conditions such as kinetic and equilibrium isotherm models involved in the removal of Ni(II) from the aqueous solutions by Trichoderma viride. The biosorbent was characterized by FTIR and SEM. The optimum biosorption conditions were determined as a function of pH, biomass dosage, contact time, initial metal ion concentration, and temperature. The maximum Ni(II) biosorption was obtained at pH 4.5. The equilibrium data were better fit by the Langmuir isotherm model than by the Freundlich isotherm. The kinetic studies indicate that the biosorption process of the metal ion Ni(II) has followed well the pseudo-second-order model. The sum of the square errors (SSE) and chi-square (χ2) tests were also carried out to find the best fit kinetic model and adsorption isotherm. The maximum biosorption capacity (qm) of T. viride biomass was found to be 47.6 mg/g for Ni(II) ion. Therefore, it can be concluded that T. viride biomass was effective and low-cost potential adsorbent to remove the toxic metal Ni(II) from aqueous solutions. The recovery process of Ni(II) from T. viride biomass was found to be higher than 98% by using 0.25 M HNO3. Besides the application of removal of toxic metal Ni(II) from aqueous solutions, the biosorbent T. viride can be reused for five consecutive sorption-desorption cycles was determined.http://dx.doi.org/10.1155/2013/716098 |
spellingShingle | P. Sujatha V. Kalarani B. Naresh Kumar Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride Journal of Chemistry |
title | Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride |
title_full | Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride |
title_fullStr | Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride |
title_full_unstemmed | Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride |
title_short | Effective Biosorption of Nickel(II) from Aqueous Solutions Using Trichoderma viride |
title_sort | effective biosorption of nickel ii from aqueous solutions using trichoderma viride |
url | http://dx.doi.org/10.1155/2013/716098 |
work_keys_str_mv | AT psujatha effectivebiosorptionofnickeliifromaqueoussolutionsusingtrichodermaviride AT vkalarani effectivebiosorptionofnickeliifromaqueoussolutionsusingtrichodermaviride AT bnareshkumar effectivebiosorptionofnickeliifromaqueoussolutionsusingtrichodermaviride |