Removal of Organophosphonate Herbicide: Adsorption onto Nanosilica

Glyphosate (IUPAC name: N-(phosphonomethyl)glycine) is a globally used phosphorous herbicide. Efficient technologies are currently unavailable for glyphosate removal. In this study, nanosilica functionalized with aminopropyl groups was synthesized and studied for glyphosate removal by adsorption. Th...

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Bibliographic Details
Main Authors: Violeta-Carolina Niculescu, Diana Ionela Popescu (Stegarus), Roxana-Elena Ionete, Irina Petreanu
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Proceedings
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Online Access:https://www.mdpi.com/2504-3900/90/1/115
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Summary:Glyphosate (IUPAC name: N-(phosphonomethyl)glycine) is a globally used phosphorous herbicide. Efficient technologies are currently unavailable for glyphosate removal. In this study, nanosilica functionalized with aminopropyl groups was synthesized and studied for glyphosate removal by adsorption. The material was characterized by carrying out SEM, TG, FTIR, BET surface area and pore size distribution measurements. The results showed that the nanosilica was better suited for glyphosate adsorption following the Henry isotherm model, with the reaction being spontaneous and feasible. The performance (quantitative adsorption and complete nanosilica recovery) is worthy of note, considering that the sorbent can be regenerated and reused for at least five cycles.
ISSN:2504-3900