Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application
This research identified the type of gel in the modified-recycled poly (ethylene terephthalate) (modified-rPET) filament, with various content of heat stabilizer, Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate. The content of the heat stabilizer used in this study were 0,...
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EDP Sciences
2025-01-01
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| Series: | E3S Web of Conferences |
| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/10/e3sconf_ri2c2025_01005.pdf |
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| author | Parneam Nismar Na Ayutthaya Siriorn Isarankura Sukhawipat Nathapong |
| author_facet | Parneam Nismar Na Ayutthaya Siriorn Isarankura Sukhawipat Nathapong |
| author_sort | Parneam Nismar |
| collection | DOAJ |
| description | This research identified the type of gel in the modified-recycled poly (ethylene terephthalate) (modified-rPET) filament, with various content of heat stabilizer, Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate. The content of the heat stabilizer used in this study were 0, 0.05, 0.1, 0.2, 0.3, 0.4 and 0.5 pph. Gel characteristics of the modified-rPET filament were characterized by using the hot stage microscopy technique. It was found that gels with heat stabilizer at 0-0.3 pph showed the unmeltgel formation characteristic. On the other hand, the addition of heat stabilizer at 0.4-0.5 pph showed the formation of crosslinked-gel characteristic, this gel does not melt even if the temperature reached to the melting temperature. This gel affects the process-ability of 3D printing. Therefore, it becomes clogged at the nozzle of 3D printer. Furthermore, this research also determined the crosslinked-gel contents inside the modified-rPET filaments, with various content of heat stabilizer, by a solvent extraction technique. Using trifluoroacetic acid/dichloromethane blended solution, it was found that at increase of the heat stabilizer content, the higher the content of crosslinked gel were observed significantly. |
| format | Article |
| id | doaj-art-5d331f5ea0694fb68508a585d4117b4f |
| institution | Kabale University |
| issn | 2267-1242 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj-art-5d331f5ea0694fb68508a585d4117b4f2025-02-05T10:50:19ZengEDP SciencesE3S Web of Conferences2267-12422025-01-016100100510.1051/e3sconf/202561001005e3sconf_ri2c2025_01005Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament applicationParneam Nismar0Na Ayutthaya Siriorn Isarankura1Sukhawipat Nathapong2Department of Power Engineering Technology, College of Industrial Technology, King Mongkut’s University of Technology North BangkokDepartment of Power Engineering Technology, College of Industrial Technology, King Mongkut’s University of Technology North BangkokCenter of Aircraft and Defence Technology (CADeT), Techno Park, King Mongkut’s University of Technology North BangkokThis research identified the type of gel in the modified-recycled poly (ethylene terephthalate) (modified-rPET) filament, with various content of heat stabilizer, Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate. The content of the heat stabilizer used in this study were 0, 0.05, 0.1, 0.2, 0.3, 0.4 and 0.5 pph. Gel characteristics of the modified-rPET filament were characterized by using the hot stage microscopy technique. It was found that gels with heat stabilizer at 0-0.3 pph showed the unmeltgel formation characteristic. On the other hand, the addition of heat stabilizer at 0.4-0.5 pph showed the formation of crosslinked-gel characteristic, this gel does not melt even if the temperature reached to the melting temperature. This gel affects the process-ability of 3D printing. Therefore, it becomes clogged at the nozzle of 3D printer. Furthermore, this research also determined the crosslinked-gel contents inside the modified-rPET filaments, with various content of heat stabilizer, by a solvent extraction technique. Using trifluoroacetic acid/dichloromethane blended solution, it was found that at increase of the heat stabilizer content, the higher the content of crosslinked gel were observed significantly.https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/10/e3sconf_ri2c2025_01005.pdf |
| spellingShingle | Parneam Nismar Na Ayutthaya Siriorn Isarankura Sukhawipat Nathapong Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application E3S Web of Conferences |
| title | Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application |
| title_full | Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application |
| title_fullStr | Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application |
| title_full_unstemmed | Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application |
| title_short | Effect of heat stabilizer content on the gel characteristic of the modified-recycled PET for 3D printing filament application |
| title_sort | effect of heat stabilizer content on the gel characteristic of the modified recycled pet for 3d printing filament application |
| url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/10/e3sconf_ri2c2025_01005.pdf |
| work_keys_str_mv | AT parneamnismar effectofheatstabilizercontentonthegelcharacteristicofthemodifiedrecycledpetfor3dprintingfilamentapplication AT naayutthayasiriornisarankura effectofheatstabilizercontentonthegelcharacteristicofthemodifiedrecycledpetfor3dprintingfilamentapplication AT sukhawipatnathapong effectofheatstabilizercontentonthegelcharacteristicofthemodifiedrecycledpetfor3dprintingfilamentapplication |