A New 3D Coordination Polymer of Bismuth with Nicotinic Acid N-Oxide
The new three-dimensional coordination polymer {[Bi(NNO)2(NO3)]·1.5H2O}n (1, NNO− = nicotinate N-oxide) was synthesized and characterized by elemental analysis, IR and 1H-NMR spectroscopy, as well as single-crystal X-ray diffraction analysis. 1 crystallizes in the monoclinic space group C2/c. The cr...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/845810 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The new three-dimensional coordination polymer {[Bi(NNO)2(NO3)]·1.5H2O}n (1, NNO− = nicotinate N-oxide) was synthesized and characterized by elemental analysis, IR and 1H-NMR spectroscopy, as well as single-crystal X-ray diffraction analysis. 1 crystallizes in the monoclinic space group C2/c. The crystal structure consists of a rectangular-shaped grid constructed with NNO linkers. Cavities of a diameter of 7.9–8.3 Å2 are filled with disordered water molecules. The thermal stability of the compound was evaluated by thermogravimetric analysis. |
|---|---|
| ISSN: | 2090-9063 2090-9071 |