Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study

Proton exchange membrane fuel cells (PEMFC) are widely used in transportation systems owing to their desirable characteristics such as high efficacy and low operating temperature. However, the fuel cell systems exhibit load changes as well as voltage and power losses so as to reduce dependence on th...

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Main Authors: Bin Xia, Pengyan Guo, Xinjing Wei, Hehui Zong
Format: Article
Language:English
Published: Wiley 2023-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2023/1346872
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author Bin Xia
Pengyan Guo
Xinjing Wei
Hehui Zong
author_facet Bin Xia
Pengyan Guo
Xinjing Wei
Hehui Zong
author_sort Bin Xia
collection DOAJ
description Proton exchange membrane fuel cells (PEMFC) are widely used in transportation systems owing to their desirable characteristics such as high efficacy and low operating temperature. However, the fuel cell systems exhibit load changes as well as voltage and power losses so as to reduce dependence on the battery. The aim of the present study was to explore the composition and basic working principle of PEMFC. A PEMFC electrochemical reaction model was then established according to the electrochemical reaction principle of fuel cell to evaluate the effects of Nernst electromotive force, activation overvoltage, Ohmic overvoltage, concentration overvoltage, and electric double layer. The effects of activation loss, concentration loss, and Ohmic loss on the fuel cell were evaluated through simulation analysis. The effect of various factors on the dynamic output of a 60 kW PEMFC was explored through dynamic simulations. The findings showed that a change in current modulated a change in voltage through the Ohmic loss equivalent resistance. The activation loss equivalent resistance and the concentration loss equivalent resistance decreased the voltage loss owing to the presence of the capacitor. The output voltage of the fuel cell decreased with an increase in load current, whereas the output power increased with an increase in load current. Increase in partial pressure of oxygen caused an increase in output power and output voltage of the cell. The internal chemical reaction rate and the voltage output of the fuel cell increases with an increase in the working temperature. The findings of this study provide a basis for conducting further studies to produce efficient fuel cells for application in various systems.
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spelling doaj-art-5a2ca0da5d414d00951f5d00a0cce0882025-08-20T03:34:58ZengWileyAdvances in Materials Science and Engineering1687-84422023-01-01202310.1155/2023/1346872Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation StudyBin Xia0Pengyan Guo1Xinjing Wei2Hehui Zong3Henan Agricultural UniversityNorth China University of Water Resources and Electric PowerNorth China University of Water Resources and Electric PowerNorth China University of Water Resources and Electric PowerProton exchange membrane fuel cells (PEMFC) are widely used in transportation systems owing to their desirable characteristics such as high efficacy and low operating temperature. However, the fuel cell systems exhibit load changes as well as voltage and power losses so as to reduce dependence on the battery. The aim of the present study was to explore the composition and basic working principle of PEMFC. A PEMFC electrochemical reaction model was then established according to the electrochemical reaction principle of fuel cell to evaluate the effects of Nernst electromotive force, activation overvoltage, Ohmic overvoltage, concentration overvoltage, and electric double layer. The effects of activation loss, concentration loss, and Ohmic loss on the fuel cell were evaluated through simulation analysis. The effect of various factors on the dynamic output of a 60 kW PEMFC was explored through dynamic simulations. The findings showed that a change in current modulated a change in voltage through the Ohmic loss equivalent resistance. The activation loss equivalent resistance and the concentration loss equivalent resistance decreased the voltage loss owing to the presence of the capacitor. The output voltage of the fuel cell decreased with an increase in load current, whereas the output power increased with an increase in load current. Increase in partial pressure of oxygen caused an increase in output power and output voltage of the cell. The internal chemical reaction rate and the voltage output of the fuel cell increases with an increase in the working temperature. The findings of this study provide a basis for conducting further studies to produce efficient fuel cells for application in various systems.http://dx.doi.org/10.1155/2023/1346872
spellingShingle Bin Xia
Pengyan Guo
Xinjing Wei
Hehui Zong
Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study
Advances in Materials Science and Engineering
title Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study
title_full Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study
title_fullStr Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study
title_full_unstemmed Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study
title_short Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study
title_sort reaction gas pressure temperature and membrane water content modulate electrochemical process of a pemfc a simulation study
url http://dx.doi.org/10.1155/2023/1346872
work_keys_str_mv AT binxia reactiongaspressuretemperatureandmembranewatercontentmodulateelectrochemicalprocessofapemfcasimulationstudy
AT pengyanguo reactiongaspressuretemperatureandmembranewatercontentmodulateelectrochemicalprocessofapemfcasimulationstudy
AT xinjingwei reactiongaspressuretemperatureandmembranewatercontentmodulateelectrochemicalprocessofapemfcasimulationstudy
AT hehuizong reactiongaspressuretemperatureandmembranewatercontentmodulateelectrochemicalprocessofapemfcasimulationstudy