Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal

Hardness in water is responsible for both residential and industrial problems. Moreover, drinking hard water is suspected as the main cause of chronic kidney disease of unknown etiology (CKDu) in Sri Lanka. The major constituents that are responsible for water hardness are calcium and magnesium ions...

Full description

Saved in:
Bibliographic Details
Main Authors: Yohan L. N. Mathota Arachchige, T. D. Fernando
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2022/3774106
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832551803815723008
author Yohan L. N. Mathota Arachchige
T. D. Fernando
author_facet Yohan L. N. Mathota Arachchige
T. D. Fernando
author_sort Yohan L. N. Mathota Arachchige
collection DOAJ
description Hardness in water is responsible for both residential and industrial problems. Moreover, drinking hard water is suspected as the main cause of chronic kidney disease of unknown etiology (CKDu) in Sri Lanka. The major constituents that are responsible for water hardness are calcium and magnesium ions. In this study, a composite was synthesized using activated carbon of Strychnos potatorum seeds (ACSP) and acrylamide to remove hardness in drinking water. The synthesized composite was characterized using Fourier transform infrared-attenuated total reflection (FTIR-ATR) spectroscopy and scanning electron microscope (SEM). According to this study, the process of removal of hardness depends on the contact time, adsorbent dosage, initial contents, and pH of the solution. The adsorption data were well fitted to the Freundlich isotherm and the pseudo-second-order kinetic models. Furthermore, environmental samples collected from Anuradhapura, Sri Lanka, which is well known for water with high hardness, were treated with an adsorbent, and hardness was reduced effectively. Moreover, the adsorption appeared to be spontaneous in nature. Finally, it can be concluded that this adsorbent can be used as an effective hardness-removing agent.
format Article
id doaj-art-5a0ff777465544e7a30ad4a6fcff1e5e
institution Kabale University
issn 2090-9071
language English
publishDate 2022-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-5a0ff777465544e7a30ad4a6fcff1e5e2025-02-03T06:00:26ZengWileyJournal of Chemistry2090-90712022-01-01202210.1155/2022/3774106Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness RemovalYohan L. N. Mathota Arachchige0T. D. Fernando1Department of ChemistryDepartment of ChemistryHardness in water is responsible for both residential and industrial problems. Moreover, drinking hard water is suspected as the main cause of chronic kidney disease of unknown etiology (CKDu) in Sri Lanka. The major constituents that are responsible for water hardness are calcium and magnesium ions. In this study, a composite was synthesized using activated carbon of Strychnos potatorum seeds (ACSP) and acrylamide to remove hardness in drinking water. The synthesized composite was characterized using Fourier transform infrared-attenuated total reflection (FTIR-ATR) spectroscopy and scanning electron microscope (SEM). According to this study, the process of removal of hardness depends on the contact time, adsorbent dosage, initial contents, and pH of the solution. The adsorption data were well fitted to the Freundlich isotherm and the pseudo-second-order kinetic models. Furthermore, environmental samples collected from Anuradhapura, Sri Lanka, which is well known for water with high hardness, were treated with an adsorbent, and hardness was reduced effectively. Moreover, the adsorption appeared to be spontaneous in nature. Finally, it can be concluded that this adsorbent can be used as an effective hardness-removing agent.http://dx.doi.org/10.1155/2022/3774106
spellingShingle Yohan L. N. Mathota Arachchige
T. D. Fernando
Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal
Journal of Chemistry
title Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal
title_full Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal
title_fullStr Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal
title_full_unstemmed Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal
title_short Equilibrium Isotherms, Kinetics, and Thermodynamic Mechanisms of a Novel Polyacrylamide-Strychnos potatorum Seed-Derived Activated Carbon Composite for Aqueous Hardness Removal
title_sort equilibrium isotherms kinetics and thermodynamic mechanisms of a novel polyacrylamide strychnos potatorum seed derived activated carbon composite for aqueous hardness removal
url http://dx.doi.org/10.1155/2022/3774106
work_keys_str_mv AT yohanlnmathotaarachchige equilibriumisothermskineticsandthermodynamicmechanismsofanovelpolyacrylamidestrychnospotatorumseedderivedactivatedcarboncompositeforaqueoushardnessremoval
AT tdfernando equilibriumisothermskineticsandthermodynamicmechanismsofanovelpolyacrylamidestrychnospotatorumseedderivedactivatedcarboncompositeforaqueoushardnessremoval