Enhanced corrosion resistance of Ti65 alloys through chromium magnetron sputtering and laser remelting: A synergistic surface engineering strategy

Near-α titanium alloy exhibits significant application potential in aerospace and chemical industries due to its exceptional mechanical strength and corrosion resistance. However, its performance degradation under chloride-rich environments (e.g., marine applications) necessitates surface engineerin...

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Bibliographic Details
Main Authors: Xinguo Chen, Wanming Li, Naixu Wang, Meng Qi, Yujing Liu, Zibo Zhao
Format: Article
Language:English
Published: Elsevier 2025-05-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425011287
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Summary:Near-α titanium alloy exhibits significant application potential in aerospace and chemical industries due to its exceptional mechanical strength and corrosion resistance. However, its performance degradation under chloride-rich environments (e.g., marine applications) necessitates surface engineering interventions. The Ti65 alloy, despite its outstanding mechanical properties, requires further surface optimization to enhance its corrosion resistance. This study develops a hybrid surface modification strategy that combines Cr magnetron sputtering with laser remelting to enhance the alloy's corrosion resistance. Systematic electrochemical testing in 3.5 wt% NaCl solution demonstrates a dual-protection mechanism: Cr solid-solution strengthening within the substrate matrix significantly improves corrosion resistance through enhanced passivation stability; the subsequent laser-remelted coating establishes a metallurgically bonded barrier layer, reducing corrosion current density from 5.0 × 10−7 A/cm2 (Ti65 substrates) to 1.2 × 10−7 A/cm2. This multiscale surface engineering approach offers a viable solution for deploying Ti65 alloys in marine and offshore applications where chloride-induced degradation prevails.
ISSN:2238-7854