Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration

Food safety assurance is crucial, particularly in identifying prohibited colors like brilliant blue (BB) that may pose significant health risks when used in food products. Surface plasmon resonance (SPR) biosensors provide a reliable, label-free method for highly sensitive detection of food adultera...

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Main Authors: Nasih Hma Salah, Baljinder Kaur, Hogr M. Rasul, Yesudasu Vasimalla, Chella Santhosh, Ramachandran Balaji, S. R. Srither, Santosh Kumar
Format: Article
Language:English
Published: IEEE 2024-01-01
Series:IEEE Open Journal of Nanotechnology
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Online Access:https://ieeexplore.ieee.org/document/10726679/
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author Nasih Hma Salah
Baljinder Kaur
Hogr M. Rasul
Yesudasu Vasimalla
Chella Santhosh
Ramachandran Balaji
S. R. Srither
Santosh Kumar
author_facet Nasih Hma Salah
Baljinder Kaur
Hogr M. Rasul
Yesudasu Vasimalla
Chella Santhosh
Ramachandran Balaji
S. R. Srither
Santosh Kumar
author_sort Nasih Hma Salah
collection DOAJ
description Food safety assurance is crucial, particularly in identifying prohibited colors like brilliant blue (BB) that may pose significant health risks when used in food products. Surface plasmon resonance (SPR) biosensors provide a reliable, label-free method for highly sensitive detection of food adulterants. In this study, we present a novel gallium sulfide (GaS)-immobilized optical fiber SPR sensor designed for the rapid, real-time detection of BB synthetic dye. The proposed sensor is comprised of a high birefringence layer (HBL) core with non-added formaldehyde (NaF) cladding, silver (Ag) as the plasmonic metal, and GaS for enhanced detection sensitivity. To determine the sensor performance, the wavelength-dependent response was measured at different refractive indices (RIs), together with sensitivity and figure of merit (FOM) over the wavelength range of 400 nm to 1000 nm. The parameters were evaluated in a sensing medium consisting of water and BB under concentrations ranging from 10 mM to 600 mM. Moreover, the distribution of electromagnetic fields across the multilayer structures of the sensor, particularly at the interfaces between Ag-GaS and GaS-analytes, was investigated. At a 10 mM concentration, the optimized Ag-GaS-based sensor, consisting of 70 nm Ag and 3 nm GaS layers at an incidence angle of 85&#x00B0;, achieves a maximum sensitivity of 5119.6 nm&#x002F;RIU and FOM of 255.98 RIU<sup>-1</sup>. The obtained results illustrate the sensor has the potential to detect non-approved colors like BB in food items with great sensitivity and accuracy.
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spelling doaj-art-595b13147fb7432fad1c960d6cca26bb2025-01-24T00:02:24ZengIEEEIEEE Open Journal of Nanotechnology2644-12922024-01-0159810610.1109/OJNANO.2024.348440810726679Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food AdulterationNasih Hma Salah0https://orcid.org/0000-0001-9168-6834Baljinder Kaur1https://orcid.org/0000-0002-0000-4576Hogr M. Rasul2https://orcid.org/0009-0007-4606-4092Yesudasu Vasimalla3https://orcid.org/0000-0002-5037-2318Chella Santhosh4Ramachandran Balaji5https://orcid.org/0000-0002-1868-2308S. R. Srither6Santosh Kumar7https://orcid.org/0000-0003-4149-0096Department of Physics, Salahaddin University, Erbil, IraqDepartment of Physics, Madhav Institute of Technology &amp; Science (MITS), Gwalior, IndiaDepartment of Physics, Salahaddin University, Erbil, IraqCentre of Excellence for Nanotechnology, Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Guntur, IndiaCentre of Excellence for Nanotechnology, Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Guntur, IndiaCentre of Excellence for Nanotechnology, Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Guntur, IndiaCentre of Excellence for Nanotechnology, Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Guntur, IndiaCentre of Excellence for Nanotechnology, Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Guntur, IndiaFood safety assurance is crucial, particularly in identifying prohibited colors like brilliant blue (BB) that may pose significant health risks when used in food products. Surface plasmon resonance (SPR) biosensors provide a reliable, label-free method for highly sensitive detection of food adulterants. In this study, we present a novel gallium sulfide (GaS)-immobilized optical fiber SPR sensor designed for the rapid, real-time detection of BB synthetic dye. The proposed sensor is comprised of a high birefringence layer (HBL) core with non-added formaldehyde (NaF) cladding, silver (Ag) as the plasmonic metal, and GaS for enhanced detection sensitivity. To determine the sensor performance, the wavelength-dependent response was measured at different refractive indices (RIs), together with sensitivity and figure of merit (FOM) over the wavelength range of 400 nm to 1000 nm. The parameters were evaluated in a sensing medium consisting of water and BB under concentrations ranging from 10 mM to 600 mM. Moreover, the distribution of electromagnetic fields across the multilayer structures of the sensor, particularly at the interfaces between Ag-GaS and GaS-analytes, was investigated. At a 10 mM concentration, the optimized Ag-GaS-based sensor, consisting of 70 nm Ag and 3 nm GaS layers at an incidence angle of 85&#x00B0;, achieves a maximum sensitivity of 5119.6 nm&#x002F;RIU and FOM of 255.98 RIU<sup>-1</sup>. The obtained results illustrate the sensor has the potential to detect non-approved colors like BB in food items with great sensitivity and accuracy.https://ieeexplore.ieee.org/document/10726679/Optical fiber biosensorgallium sulfidebrilliant blue (BB) detectionresponsible consumption and productionzero hungergood health and well-being
spellingShingle Nasih Hma Salah
Baljinder Kaur
Hogr M. Rasul
Yesudasu Vasimalla
Chella Santhosh
Ramachandran Balaji
S. R. Srither
Santosh Kumar
Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration
IEEE Open Journal of Nanotechnology
Optical fiber biosensor
gallium sulfide
brilliant blue (BB) detection
responsible consumption and production
zero hunger
good health and well-being
title Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration
title_full Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration
title_fullStr Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration
title_full_unstemmed Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration
title_short Gallium Sulfide-Immobilized Optical Fiber-Based SPR Sensor for Detection of Brilliant Blue Food Adulteration
title_sort gallium sulfide immobilized optical fiber based spr sensor for detection of brilliant blue food adulteration
topic Optical fiber biosensor
gallium sulfide
brilliant blue (BB) detection
responsible consumption and production
zero hunger
good health and well-being
url https://ieeexplore.ieee.org/document/10726679/
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