Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees

Petrographic and geochemical analyses (δ18O, δ13C, 87Sr/86Sr, clumped isotopes, and elemental composition) coupled with field structural data of synkinematic calcite veins, fault rocks, and host rocks are used to reconstruct the episodic evolution of an outstanding exposed thrust zone in the Souther...

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Main Authors: Daniel Muñoz-López, David Cruset, Irene Cantarero, Antonio Benedicto, Cédric M. John, Anna Travé
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Geofluids
Online Access:http://dx.doi.org/10.1155/2020/8815729
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author Daniel Muñoz-López
David Cruset
Irene Cantarero
Antonio Benedicto
Cédric M. John
Anna Travé
author_facet Daniel Muñoz-López
David Cruset
Irene Cantarero
Antonio Benedicto
Cédric M. John
Anna Travé
author_sort Daniel Muñoz-López
collection DOAJ
description Petrographic and geochemical analyses (δ18O, δ13C, 87Sr/86Sr, clumped isotopes, and elemental composition) coupled with field structural data of synkinematic calcite veins, fault rocks, and host rocks are used to reconstruct the episodic evolution of an outstanding exposed thrust zone in the Southern Pyrenees and to evaluate the fault behavior as a conduit or barrier to fluid migration. The selected thrust displaces the steeply dipping southern limb of the Sant Corneli-Bóixols anticline, juxtaposing a Cenomanian-Turonian carbonate unit against a Coniacian carbonate sequence. Successive deformation events are recorded by distinct fracture systems and related calcite veins, highlighting (i) an episodic evolution of the thrust zone, resulting from an upward migration of the fault tip (process zone development) before growth of the fault (thrust slip plane propagation), and (ii) compartmentalization of the thrust fault zone, leading to different structural and fluid flow histories in the footwall and hanging wall. Fractures within the footwall comprise three systematically oriented fracture sets (F1, F2, and F3), each sealed by a separate generation calcite cement, and a randomly oriented fracture system (mosaic to chaotic breccia), cemented by the same cements as fracture sets F1 and F2. The formation of fractures F1 and F2 and the mosaic to chaotic breccia is consistent with dilatant fracturing within the process zone (around the fault tip) during initial fault growth, whereas the formation of the latest fracture system points to hybrid shear-dilational failure during propagation of the fault. The continuous formation of different fracture systems and related calcite cementation phases evidences that the structural permeability in the footwall was transient and that the fluid pathways and regime evolved due to successive events of fracture opening and calcite cementation. Clumped isotopes evidence a progressive increase in precipitation temperatures from around 50°C to 117°C approximately, interpreted as burial increase linked to thrust sheet emplacement. During this period, the source of fluid changed from meteoric fluids to evolved meteoric fluids due to the water-rock interaction at increasing depths and temperatures. Contrary to the footwall, within the hanging wall, only randomly oriented fractures are recognized and the resulting crackle proto-breccia is sealed by a later and different calcite cement, which is also observed in the main fault plane and in the fault core. This cement precipitated from formation fluids, at around 95°C, that circulated along the fault core and in the hanging wall block, again supporting the interpretation of compartmentalization of the thrust structure. The integration of these data reveals that the studied thrust fault acted as a transverse barrier, dividing the thrust zone into two separate fluid compartments, and a longitudinal drain for migration of fluids. This study also highlights the similarity in deformation processes and mechanisms linked to the evolution of fault zones in compressional and extensional regimes involving carbonate rocks.
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spelling doaj-art-58f2a7a2d5ef45058182eb9d501d1c2c2025-02-03T06:46:46ZengWileyGeofluids1468-81151468-81232020-01-01202010.1155/2020/88157298815729Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern PyreneesDaniel Muñoz-López0David Cruset1Irene Cantarero2Antonio Benedicto3Cédric M. John4Anna Travé5Departament de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), Martí i Franquès s/n, 08028 Barcelona, SpainGroup of Dynamics of the Lithosphere (GDL), Geosciences Barcelona, GEO3BCN-CSIC, Lluís Solé i Sabarís s/n, 08028 Barcelona, SpainDepartament de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), Martí i Franquès s/n, 08028 Barcelona, SpainUMR CNR GEOPS, Université Paris-Saclay, 91405 Orsay, FranceDepartment of Earth Science and Engineering, Imperial College London, London SW7 2BP, UKDepartament de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Ciències de la Terra, Universitat de Barcelona (UB), Martí i Franquès s/n, 08028 Barcelona, SpainPetrographic and geochemical analyses (δ18O, δ13C, 87Sr/86Sr, clumped isotopes, and elemental composition) coupled with field structural data of synkinematic calcite veins, fault rocks, and host rocks are used to reconstruct the episodic evolution of an outstanding exposed thrust zone in the Southern Pyrenees and to evaluate the fault behavior as a conduit or barrier to fluid migration. The selected thrust displaces the steeply dipping southern limb of the Sant Corneli-Bóixols anticline, juxtaposing a Cenomanian-Turonian carbonate unit against a Coniacian carbonate sequence. Successive deformation events are recorded by distinct fracture systems and related calcite veins, highlighting (i) an episodic evolution of the thrust zone, resulting from an upward migration of the fault tip (process zone development) before growth of the fault (thrust slip plane propagation), and (ii) compartmentalization of the thrust fault zone, leading to different structural and fluid flow histories in the footwall and hanging wall. Fractures within the footwall comprise three systematically oriented fracture sets (F1, F2, and F3), each sealed by a separate generation calcite cement, and a randomly oriented fracture system (mosaic to chaotic breccia), cemented by the same cements as fracture sets F1 and F2. The formation of fractures F1 and F2 and the mosaic to chaotic breccia is consistent with dilatant fracturing within the process zone (around the fault tip) during initial fault growth, whereas the formation of the latest fracture system points to hybrid shear-dilational failure during propagation of the fault. The continuous formation of different fracture systems and related calcite cementation phases evidences that the structural permeability in the footwall was transient and that the fluid pathways and regime evolved due to successive events of fracture opening and calcite cementation. Clumped isotopes evidence a progressive increase in precipitation temperatures from around 50°C to 117°C approximately, interpreted as burial increase linked to thrust sheet emplacement. During this period, the source of fluid changed from meteoric fluids to evolved meteoric fluids due to the water-rock interaction at increasing depths and temperatures. Contrary to the footwall, within the hanging wall, only randomly oriented fractures are recognized and the resulting crackle proto-breccia is sealed by a later and different calcite cement, which is also observed in the main fault plane and in the fault core. This cement precipitated from formation fluids, at around 95°C, that circulated along the fault core and in the hanging wall block, again supporting the interpretation of compartmentalization of the thrust structure. The integration of these data reveals that the studied thrust fault acted as a transverse barrier, dividing the thrust zone into two separate fluid compartments, and a longitudinal drain for migration of fluids. This study also highlights the similarity in deformation processes and mechanisms linked to the evolution of fault zones in compressional and extensional regimes involving carbonate rocks.http://dx.doi.org/10.1155/2020/8815729
spellingShingle Daniel Muñoz-López
David Cruset
Irene Cantarero
Antonio Benedicto
Cédric M. John
Anna Travé
Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees
Geofluids
title Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees
title_full Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees
title_fullStr Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees
title_full_unstemmed Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees
title_short Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees
title_sort fluid dynamics in a thrust fault inferred from petrology and geochemistry of calcite veins an example from the southern pyrenees
url http://dx.doi.org/10.1155/2020/8815729
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