Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines
Tin(IV) complexes of 7-substituted 6,7-benzo-1,5-dizepines have been synthesized in absolute alcoholic medium. Elemental analysis indicates that the complexes have 1:2 stoichiometry of the type L2SnCl4, TGA data support this conclusion. Molar conductance values in DMF at 10–3 M suggest that, these c...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2008-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2008/582797 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832558317135724544 |
|---|---|
| author | Suresh Padaki Srinivas T. Suresh M. Revanasiddappa Syed Khasim |
| author_facet | Suresh Padaki Srinivas T. Suresh M. Revanasiddappa Syed Khasim |
| author_sort | Suresh |
| collection | DOAJ |
| description | Tin(IV) complexes of 7-substituted 6,7-benzo-1,5-dizepines have been synthesized in absolute alcoholic medium. Elemental analysis indicates that the complexes have 1:2 stoichiometry of the type L2SnCl4, TGA data support this conclusion. Molar conductance values in DMF at 10–3 M suggest that, these complexes are non-electrolytes. Infrared spectral data shows the involvement of C=N and NH groups in coordination with the metal ion. X-ray diffraction pattern of few representative complexes indicate that, these are having simple cubic crystal structure. The energy of activation and order of reaction are calculated using TGA data of the complexes. All these information support that Sn(IV) in these complexes exhibits coordination number eight. |
| format | Article |
| id | doaj-art-570d78d69ab942f581293b40dd217125 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2008-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-570d78d69ab942f581293b40dd2171252025-02-03T01:32:43ZengWileyE-Journal of Chemistry0973-49452090-98102008-01-015362763310.1155/2008/582797Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-BenzodiazepinesSuresh0Padaki Srinivas1T. Suresh2M. Revanasiddappa3Syed Khasim4Department of Applied Science and Biotechnology, Bellary Engineering College, Bellary - 583 104, Karnataka, IndiaDepartment of Chemistry, P.D.A. College of Engineering, Gulbarga - 585 102, Karnataka, IndiaDepartment of Industrial Chemistry, Gulbarga University Post Graduate Centre, Vinayaka Nagar, Cantonment, Bellary- 583 104, Karnataka, IndiaDepartment of Chemistry, PES School of Engineering, Hosur Road, Bangalore- 560 100 Karnataka, IndiaDepartment of Physics, PES School of Engineering, Hosur Road, Bangalore- 560 100 Karnataka, IndiaTin(IV) complexes of 7-substituted 6,7-benzo-1,5-dizepines have been synthesized in absolute alcoholic medium. Elemental analysis indicates that the complexes have 1:2 stoichiometry of the type L2SnCl4, TGA data support this conclusion. Molar conductance values in DMF at 10–3 M suggest that, these complexes are non-electrolytes. Infrared spectral data shows the involvement of C=N and NH groups in coordination with the metal ion. X-ray diffraction pattern of few representative complexes indicate that, these are having simple cubic crystal structure. The energy of activation and order of reaction are calculated using TGA data of the complexes. All these information support that Sn(IV) in these complexes exhibits coordination number eight.http://dx.doi.org/10.1155/2008/582797 |
| spellingShingle | Suresh Padaki Srinivas T. Suresh M. Revanasiddappa Syed Khasim Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines E-Journal of Chemistry |
| title | Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines |
| title_full | Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines |
| title_fullStr | Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines |
| title_full_unstemmed | Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines |
| title_short | Synthetic, Spectral and Thermal Studies of Tin(IV) Complexes of 1, 5-Benzodiazepines |
| title_sort | synthetic spectral and thermal studies of tin iv complexes of 1 5 benzodiazepines |
| url | http://dx.doi.org/10.1155/2008/582797 |
| work_keys_str_mv | AT suresh syntheticspectralandthermalstudiesoftinivcomplexesof15benzodiazepines AT padakisrinivas syntheticspectralandthermalstudiesoftinivcomplexesof15benzodiazepines AT tsuresh syntheticspectralandthermalstudiesoftinivcomplexesof15benzodiazepines AT mrevanasiddappa syntheticspectralandthermalstudiesoftinivcomplexesof15benzodiazepines AT syedkhasim syntheticspectralandthermalstudiesoftinivcomplexesof15benzodiazepines |