A Facile and Waste-Free Strategy to Fabricate Pt-C/TiO2 Microspheres: Enhanced Photocatalytic Performance for Hydrogen Evolution

A facile and waste-free flame thermal synthesis method was developed for preparing Pt modified C/TiO2 microspheres (Pt-C/TiO2). The photocatalysts were characterized with X-ray diffraction, field emission scanning electron microscopy, transmission electron microscope, ultraviolet-visible (UV-vis) di...

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Bibliographic Details
Main Authors: Hui Li, Xiaoyan Zhang, Xiaoli Cui
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2014/414281
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Summary:A facile and waste-free flame thermal synthesis method was developed for preparing Pt modified C/TiO2 microspheres (Pt-C/TiO2). The photocatalysts were characterized with X-ray diffraction, field emission scanning electron microscopy, transmission electron microscope, ultraviolet-visible (UV-vis) diffuse reflectance spectra, X-ray photoelectron spectroscopy, and thermogravimetry analysis. The photocatalytic activity was evaluated by hydrogen evolution from water splitting under UV-vis light illumination. Benefitting from the electron-hole separation behavior and reduced overpotential of H+/H2, remarkably enhanced hydrogen production was demonstrated and the photocatalytic hydrogen generation from 0.4 wt% Pt-C/TiO2 increased by 22 times. This study also demonstrates that the novel and facile method is highly attractive, due to its easy operation, requiring no post treatment and energy-saving features.
ISSN:1110-662X
1687-529X