Bimetallic NiCo Nanoparticles Embedded in Organic Group Functionalized Mesoporous Silica for Efficient Hydrogen Production from Ammonia Borane Hydrolysis
In this study, bimetallic NiCo nanoparticles (NPs) were encapsulated within the mesopores of carboxylic acid functionalized mesoporous silica (CMS) through the chemical reduction approach. Both NaBH<sub>4</sub> and NH<sub>3</sub>BH<sub>3</sub> were used as reducin...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2024-11-01
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| Series: | Nanomaterials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2079-4991/14/22/1818 |
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| Summary: | In this study, bimetallic NiCo nanoparticles (NPs) were encapsulated within the mesopores of carboxylic acid functionalized mesoporous silica (CMS) through the chemical reduction approach. Both NaBH<sub>4</sub> and NH<sub>3</sub>BH<sub>3</sub> were used as reducing agents to reduce the metal ions simultaneously. The resulting composite was used as a catalyst for hydrolysis of ammonia borane (NH<sub>3</sub>BH<sub>3</sub>, AB) to produce H<sub>2</sub>. The bimetallic NiCo NPs supported on carboxylic group functionalized mesoporous silica, referred to as Ni<sub>x</sub>Co<sub>100−x</sub>@CMS, exhibited significantly higher catalytic activity for AB hydrolysis compared to their monometallic counterparts. The remarkable activity of Ni<sub>x</sub>Co<sub>100−x</sub>@CMS could be ascribed to the synergistic contributions of Ni and Co, redox reaction during the hydrolysis, and the fine-tuned electronic structure. The catalytic performance of the Ni<sub>x</sub>Co<sub>100−x</sub>@CMS nanocatalyst was observed to be dependent on the composition of Ni and Co. Among all the compositions investigated, Ni<sub>40</sub>Co<sub>60</sub>@CMS demonstrated the highest catalytic activity, with a turn over frequency (TOF) of 18.95 mol<sub>H2</sub>min<sup>−1</sup>mol<sub>catalyst</sub><sup>−1</sup> and H<sub>2</sub> production rate of 8.0 L min<sup>−1</sup>g<sup>−1</sup>. The activity of Ni<sub>40</sub>Co<sub>60</sub>@CMS was approximately three times greater than that of Ni@CMS and about two times that of Co@CMS. The superior activity of Ni<sub>40</sub>Co<sub>60</sub>@CMS was attributed to its finely-tuned electronic structure, resulting from the electron transfer of Ni to Co. Furthermore, the nanocatalyst exhibited excellent durability, as the carboxylate group in the support provided a strong metal–support interaction, securely anchoring the NPs within the mesopores, preventing both agglomeration and leakage. |
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| ISSN: | 2079-4991 |