Oxygen-rich engineering of lignin-derived porous carbons through potassium activation for zinc ion hybrid capacitors

Oxygen-rich engineering of lignin-derived porous carbons through potassium activation for zinc ion hybrid capacitors

Oxygen-rich porous carbons are promising candidates for the carbon-based cathodes of zinc ion hybrid capacitors (ZIHCs). Potassium activation is a traditional and effective way to prepare oxygen-rich porous carbons. Efficient potassium activation is the key to develop high-performance oxygen-rich po...

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Bibliographic Details
Main Authors: Xueyi Liang, Caiwei Wang, Zicheng Li, Bo Chen, Xuemin Cui, Yuanyuan Ge, Zhili Li
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-06-01
Series:Resources Chemicals and Materials
Subjects:
Oxygen dopant
Lignin
Porous carbon
Potassium activation
Zinc ion hybrid capacitors
Online Access:http://www.sciencedirect.com/science/article/pii/S2772443324000588
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Summary:Oxygen-rich porous carbons are promising candidates for the carbon-based cathodes of zinc ion hybrid capacitors (ZIHCs). Potassium activation is a traditional and effective way to prepare oxygen-rich porous carbons. Efficient potassium activation is the key to develop high-performance oxygen-rich porous carbon cathodes. Herein, the alkali lignin, extracted from eucalyptus wood by geopolymer-assisted low-alkali pretreatment, is used to prepare oxygen-rich lignin-derived porous carbons (OLPCs) through KOH activation and K2CO3 activation at 700–900 °C. KOH activation constructs a hierarchical micro-mesoporous structure, while K2CO3 activation constructs a microporous structure. Furthermore, K2CO3 activation could more efficiently construct active oxygen (C = O) species than KOH activation. The OLPCs prepared by KOH/K2CO3 activations at 800 °C show the highest microporosity (78.4/87.7 %) and C = O content (5.3/8.0 at.%). Due to that C = O and micropore adsorb zinc ions, the OLPCs prepared by K2CO3 activation at 800 °C with higher C = O content and microporosity deliver superior capacitive performance (256 F g-1 at 0.1 A g-1) than that by KOH activation at 800 °C (224 F g-1 at 0.1 A g-1), and excellent cycling stability. This work provides a new insight into the sustainable preparation of oxygen-rich porous carbon cathodes through efficient potassium activation for ZIHCs.
ISSN:2772-4433

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