A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol
A new, simple, inexpensive and fast kinetic spectrophotometric method was developed for the determination of trace amounts of resorcinol over the range of 0.02-0.80 μg/mL. The method is based on the inhibitory effect of resorcinol on the formaldehyde catalyzed oxidation reaction of of cresyl violet...
Saved in:
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2010-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/359191 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832567097007276032 |
|---|---|
| author | Mohsen Keyvanfard |
| author_facet | Mohsen Keyvanfard |
| author_sort | Mohsen Keyvanfard |
| collection | DOAJ |
| description | A new, simple, inexpensive and fast kinetic spectrophotometric method was developed for the determination of trace amounts of resorcinol over the range of 0.02-0.80 μg/mL. The method is based on the inhibitory effect of resorcinol on the formaldehyde catalyzed oxidation reaction of of cresyl violet by bromate in acidic media is reported. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of cresyl violet at 596 nm with a fixed-time 0.5–2.5 min from initiation of the reaction.The detection limit is 0.017 μg/mL and relative standard deviation of 0.1 and 0.5 μg/mL resorcinol for six replicate measurements was 2.6 and 2.9 %, respectively. The method was applied to the determination of resorcinol in water samples. |
| format | Article |
| id | doaj-art-543f8591b4844b478213d169b0e4ceb3 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-543f8591b4844b478213d169b0e4ceb32025-02-03T01:02:24ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-017372773210.1155/2010/359191A New Inhibition Kinetic Spectrophotometric Method for the Determination of ResorcinolMohsen Keyvanfard0Faculty of Science, Islamic Azad University-Majlesi Branch, Isfahan, IranA new, simple, inexpensive and fast kinetic spectrophotometric method was developed for the determination of trace amounts of resorcinol over the range of 0.02-0.80 μg/mL. The method is based on the inhibitory effect of resorcinol on the formaldehyde catalyzed oxidation reaction of of cresyl violet by bromate in acidic media is reported. The reaction was monitored spectrophotometrically by measuring the decrease in absorbance of cresyl violet at 596 nm with a fixed-time 0.5–2.5 min from initiation of the reaction.The detection limit is 0.017 μg/mL and relative standard deviation of 0.1 and 0.5 μg/mL resorcinol for six replicate measurements was 2.6 and 2.9 %, respectively. The method was applied to the determination of resorcinol in water samples.http://dx.doi.org/10.1155/2010/359191 |
| spellingShingle | Mohsen Keyvanfard A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol E-Journal of Chemistry |
| title | A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol |
| title_full | A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol |
| title_fullStr | A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol |
| title_full_unstemmed | A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol |
| title_short | A New Inhibition Kinetic Spectrophotometric Method for the Determination of Resorcinol |
| title_sort | new inhibition kinetic spectrophotometric method for the determination of resorcinol |
| url | http://dx.doi.org/10.1155/2010/359191 |
| work_keys_str_mv | AT mohsenkeyvanfard anewinhibitionkineticspectrophotometricmethodforthedeterminationofresorcinol AT mohsenkeyvanfard newinhibitionkineticspectrophotometricmethodforthedeterminationofresorcinol |