Supercritical Fluid Geochemistry in Geothermal Systems

Supercritical fluids exist in the roots of many active high-temperature geothermal systems. Utilization of such supercritical resources may multiply energy production from geothermal systems; yet, their occurrence, formation mechanism, and chemical properties are poorly constrained. Flow-through exp...

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Main Authors: Matylda Heřmanská, Barbara I. Kleine, Andri Stefánsson
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Geofluids
Online Access:http://dx.doi.org/10.1155/2019/6023534
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author Matylda Heřmanská
Barbara I. Kleine
Andri Stefánsson
author_facet Matylda Heřmanská
Barbara I. Kleine
Andri Stefánsson
author_sort Matylda Heřmanská
collection DOAJ
description Supercritical fluids exist in the roots of many active high-temperature geothermal systems. Utilization of such supercritical resources may multiply energy production from geothermal systems; yet, their occurrence, formation mechanism, and chemical properties are poorly constrained. Flow-through experiments at 260°C and 400-420°C were performed to study the chemical and mineralogical changes associated with supercritical fluid formation near shallow magmatic intrusions by conductive heating and boiling of conventional subcritical geothermal fluids. Supercritical fluids formed by isobaric heating of liquid geothermal water had similar volatile element concentrations (B, C, and S) as the subcritical water. In contrast, mineral-forming element concentrations (Si, Na, K, Ca, Mg, and Cl) in the supercritical fluid were much lower. The results are consistent with the observed mineral deposition of quartz, aluminum silicates, and minor amount of salts during boiling. Similar concentration patterns have been predicted from geochemical modeling and were observed at Krafla, Iceland, for the IDDP-1 supercritical fluid discharge. The experimental results confirm previous findings that supercritical fluids may originate from conductive heating of subcritical geothermal reservoir fluids characterized by similar or lower elemental concentrations with minor input of volcanic gas.
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publishDate 2019-01-01
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series Geofluids
spelling doaj-art-53b29913a6f9438f9c2a621b37b884222025-02-03T01:28:39ZengWileyGeofluids1468-81151468-81232019-01-01201910.1155/2019/60235346023534Supercritical Fluid Geochemistry in Geothermal SystemsMatylda Heřmanská0Barbara I. Kleine1Andri Stefánsson2Institute of Earth Sciences, University of Iceland, Sturlugata 7, Reykjavík 101, IcelandInstitute of Earth Sciences, University of Iceland, Sturlugata 7, Reykjavík 101, IcelandInstitute of Earth Sciences, University of Iceland, Sturlugata 7, Reykjavík 101, IcelandSupercritical fluids exist in the roots of many active high-temperature geothermal systems. Utilization of such supercritical resources may multiply energy production from geothermal systems; yet, their occurrence, formation mechanism, and chemical properties are poorly constrained. Flow-through experiments at 260°C and 400-420°C were performed to study the chemical and mineralogical changes associated with supercritical fluid formation near shallow magmatic intrusions by conductive heating and boiling of conventional subcritical geothermal fluids. Supercritical fluids formed by isobaric heating of liquid geothermal water had similar volatile element concentrations (B, C, and S) as the subcritical water. In contrast, mineral-forming element concentrations (Si, Na, K, Ca, Mg, and Cl) in the supercritical fluid were much lower. The results are consistent with the observed mineral deposition of quartz, aluminum silicates, and minor amount of salts during boiling. Similar concentration patterns have been predicted from geochemical modeling and were observed at Krafla, Iceland, for the IDDP-1 supercritical fluid discharge. The experimental results confirm previous findings that supercritical fluids may originate from conductive heating of subcritical geothermal reservoir fluids characterized by similar or lower elemental concentrations with minor input of volcanic gas.http://dx.doi.org/10.1155/2019/6023534
spellingShingle Matylda Heřmanská
Barbara I. Kleine
Andri Stefánsson
Supercritical Fluid Geochemistry in Geothermal Systems
Geofluids
title Supercritical Fluid Geochemistry in Geothermal Systems
title_full Supercritical Fluid Geochemistry in Geothermal Systems
title_fullStr Supercritical Fluid Geochemistry in Geothermal Systems
title_full_unstemmed Supercritical Fluid Geochemistry in Geothermal Systems
title_short Supercritical Fluid Geochemistry in Geothermal Systems
title_sort supercritical fluid geochemistry in geothermal systems
url http://dx.doi.org/10.1155/2019/6023534
work_keys_str_mv AT matyldahermanska supercriticalfluidgeochemistryingeothermalsystems
AT barbaraikleine supercriticalfluidgeochemistryingeothermalsystems
AT andristefansson supercriticalfluidgeochemistryingeothermalsystems