Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes

Using the method of X-ray photoelectron spectroscopy (XPS), a comparative analysis of the structure and chemical state of multi-walled carbon nanotubes doped with nitrogen during their synthesis, as well as by high-dose irradiation with nitrogen ions, is carried out. It is shown that the chemica...

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Main Author: S. N. Nesov
Format: Article
Language:English
Published: Omsk State Technical University, Federal State Autonoumos Educational Institution of Higher Education 2020-09-01
Series:Омский научный вестник
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Online Access:https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2020/4%20(172)/94-97%20%D0%9D%D0%B5%D1%81%D0%BE%D0%B2%20%D0%A1.%20%D0%9D..pdf
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author S. N. Nesov
author_facet S. N. Nesov
author_sort S. N. Nesov
collection DOAJ
description Using the method of X-ray photoelectron spectroscopy (XPS), a comparative analysis of the structure and chemical state of multi-walled carbon nanotubes doped with nitrogen during their synthesis, as well as by high-dose irradiation with nitrogen ions, is carried out. It is shown that the chemical state of nitrogen in the walls of MWCNTs doped with various methods differs significantly. It was found that the use of ion irradiation allows one to obtain MWСNTs with a higher nitrogen concentration in the structure of the outer walls. However, there is a significant increase in the degree of imperfection of the crystal structure of the walls of carbon nanotubes and the formation of oxygencontaining functional groups. The features of the chemical state of nitrogen in the walls of MWCNTs using various alloying methods are established. The results obtained in this work can be used to develop methods for modifying the electronic structure of carbon nanostructured materials.
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language English
publishDate 2020-09-01
publisher Omsk State Technical University, Federal State Autonoumos Educational Institution of Higher Education
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spelling doaj-art-537a4f7e7d644d1eb2caf82dae82aa5b2025-02-02T12:20:52ZengOmsk State Technical University, Federal State Autonoumos Educational Institution of Higher EducationОмский научный вестник1813-82252541-75412020-09-014 (172)949710.25206/1813-8225-2020-172-94-97Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubesS. N. Nesov0Omsk Scientific Center of Siberian Branch of Russian Academy of SciencesUsing the method of X-ray photoelectron spectroscopy (XPS), a comparative analysis of the structure and chemical state of multi-walled carbon nanotubes doped with nitrogen during their synthesis, as well as by high-dose irradiation with nitrogen ions, is carried out. It is shown that the chemical state of nitrogen in the walls of MWCNTs doped with various methods differs significantly. It was found that the use of ion irradiation allows one to obtain MWСNTs with a higher nitrogen concentration in the structure of the outer walls. However, there is a significant increase in the degree of imperfection of the crystal structure of the walls of carbon nanotubes and the formation of oxygencontaining functional groups. The features of the chemical state of nitrogen in the walls of MWCNTs using various alloying methods are established. The results obtained in this work can be used to develop methods for modifying the electronic structure of carbon nanostructured materials.https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2020/4%20(172)/94-97%20%D0%9D%D0%B5%D1%81%D0%BE%D0%B2%20%D0%A1.%20%D0%9D..pdfmulti-walled carbon nanotubesx-ray photoelectron spectroscopynitrogen dopingion irradiation
spellingShingle S. N. Nesov
Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes
Омский научный вестник
multi-walled carbon nanotubes
x-ray photoelectron spectroscopy
nitrogen doping
ion irradiation
title Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes
title_full Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes
title_fullStr Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes
title_full_unstemmed Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes
title_short Comparative analysis of structure and chemical state of nitrogen-doped multi-walled carbon nanotubes
title_sort comparative analysis of structure and chemical state of nitrogen doped multi walled carbon nanotubes
topic multi-walled carbon nanotubes
x-ray photoelectron spectroscopy
nitrogen doping
ion irradiation
url https://www.omgtu.ru/general_information/media_omgtu/journal_of_omsk_research_journal/files/arhiv/2020/4%20(172)/94-97%20%D0%9D%D0%B5%D1%81%D0%BE%D0%B2%20%D0%A1.%20%D0%9D..pdf
work_keys_str_mv AT snnesov comparativeanalysisofstructureandchemicalstateofnitrogendopedmultiwalledcarbonnanotubes