MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES
1,1-Diarylethenes react with alkyl 2-oxocyclopentanecarbo-xylates in the presence of manganese triacetate leading to the formation of 1-acetoxy-3,3-diaryl-5-ethoxycarbonyl-2-oxabicyclo[3.3.O]octane or 2-(2,2-diarylethenyl)-2-ethoxycarbonylcyclopentanone in good yields. Substituents on aryl ring of t...
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Dalat University
2013-03-01
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| Series: | Tạp chí Khoa học Đại học Đà Lạt |
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| Online Access: | https://tckh.dlu.edu.vn/index.php/tckhdhdl/article/view/227 |
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| author | Huỳnh Thái Kim Ngân Nguyễn Văn Hạ |
| author_facet | Huỳnh Thái Kim Ngân Nguyễn Văn Hạ |
| author_sort | Huỳnh Thái Kim Ngân |
| collection | DOAJ |
| description | 1,1-Diarylethenes react with alkyl 2-oxocyclopentanecarbo-xylates in the presence of manganese triacetate leading to the formation of 1-acetoxy-3,3-diaryl-5-ethoxycarbonyl-2-oxabicyclo[3.3.O]octane or 2-(2,2-diarylethenyl)-2-ethoxycarbonylcyclopentanone in good yields. Substituents on aryl ring of the alkenes have remarkable influence on the product type. The reaction mechanism is discussed. |
| format | Article |
| id | doaj-art-53523a73d47849c1b0786a2fd5751710 |
| institution | Kabale University |
| issn | 0866-787X |
| language | English |
| publishDate | 2013-03-01 |
| publisher | Dalat University |
| record_format | Article |
| series | Tạp chí Khoa học Đại học Đà Lạt |
| spelling | doaj-art-53523a73d47849c1b0786a2fd57517102025-02-02T12:00:11ZengDalat UniversityTạp chí Khoa học Đại học Đà Lạt0866-787X2013-03-013110.37569/DalatUniversity.3.1.227(2013)MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVESHuỳnh Thái Kim Ngân0Nguyễn Văn Hạ1Centre for Applications of Nuclear Technique in IndustryKhoa Hóa học, Trường Đại học Đà Lạt1,1-Diarylethenes react with alkyl 2-oxocyclopentanecarbo-xylates in the presence of manganese triacetate leading to the formation of 1-acetoxy-3,3-diaryl-5-ethoxycarbonyl-2-oxabicyclo[3.3.O]octane or 2-(2,2-diarylethenyl)-2-ethoxycarbonylcyclopentanone in good yields. Substituents on aryl ring of the alkenes have remarkable influence on the product type. The reaction mechanism is discussed.https://tckh.dlu.edu.vn/index.php/tckhdhdl/article/view/227Manganese(Ill) acetate2-oxabicyclo[3.3.O]octanesOxidative cycloaddition |
| spellingShingle | Huỳnh Thái Kim Ngân Nguyễn Văn Hạ MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES Tạp chí Khoa học Đại học Đà Lạt Manganese(Ill) acetate 2-oxabicyclo[3.3.O]octanes Oxidative cycloaddition |
| title | MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES |
| title_full | MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES |
| title_fullStr | MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES |
| title_full_unstemmed | MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES |
| title_short | MANGANESE(III)-BASED REACTION OF l,l-DIARYLETHENES WITH ALKYL 2-0XOCYCLOPENTANECARBOXYLATES: AN EFFICIENT ROUTE TO 2-0XABICYCLO[3.3.0]OCTANE DERIVATIVES |
| title_sort | manganese iii based reaction of l l diarylethenes with alkyl 2 0xocyclopentanecarboxylates an efficient route to 2 0xabicyclo 3 3 0 octane derivatives |
| topic | Manganese(Ill) acetate 2-oxabicyclo[3.3.O]octanes Oxidative cycloaddition |
| url | https://tckh.dlu.edu.vn/index.php/tckhdhdl/article/view/227 |
| work_keys_str_mv | AT huynhthaikimngan manganeseiiibasedreactionoflldiaryletheneswithalkyl20xocyclopentanecarboxylatesanefficientrouteto20xabicyclo330octanederivatives AT nguyenvanha manganeseiiibasedreactionoflldiaryletheneswithalkyl20xocyclopentanecarboxylatesanefficientrouteto20xabicyclo330octanederivatives |