Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase
A highly selective diallylation reaction of anilines with allyl bromide was achieved in aqueous alcohol solution in the presence of potassium carbonate and without the use of any catalyst. The reaction tolerates a wide range of functionalities, and various tertiary amines were obtained in the yield...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/989285 |
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| _version_ | 1832568356419403776 |
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| author | Zhengyin Du Xiaohong Wei Wenwen Zhang Yuanmin Zhang Qunji Xue |
| author_facet | Zhengyin Du Xiaohong Wei Wenwen Zhang Yuanmin Zhang Qunji Xue |
| author_sort | Zhengyin Du |
| collection | DOAJ |
| description | A highly selective diallylation reaction of anilines with allyl bromide was achieved in aqueous alcohol solution in the presence of potassium carbonate and without the use of any catalyst. The reaction tolerates a wide range of functionalities, and various tertiary amines were obtained in the yield of up to 99% with complete conversion of anilines. |
| format | Article |
| id | doaj-art-52e99dc11bb24ceaa1b86e411366c015 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-52e99dc11bb24ceaa1b86e411366c0152025-02-03T00:59:17ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/989285989285Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous PhaseZhengyin Du0Xiaohong Wei1Wenwen Zhang2Yuanmin Zhang3Qunji Xue4Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, ChinaA highly selective diallylation reaction of anilines with allyl bromide was achieved in aqueous alcohol solution in the presence of potassium carbonate and without the use of any catalyst. The reaction tolerates a wide range of functionalities, and various tertiary amines were obtained in the yield of up to 99% with complete conversion of anilines.http://dx.doi.org/10.1155/2013/989285 |
| spellingShingle | Zhengyin Du Xiaohong Wei Wenwen Zhang Yuanmin Zhang Qunji Xue Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase Journal of Chemistry |
| title | Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase |
| title_full | Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase |
| title_fullStr | Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase |
| title_full_unstemmed | Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase |
| title_short | Catalyst-Free and Highly Selective N,N-Diallylation of Anilines in Aqueous Phase |
| title_sort | catalyst free and highly selective n n diallylation of anilines in aqueous phase |
| url | http://dx.doi.org/10.1155/2013/989285 |
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