Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose
The oxaloyl carboxymethyl cellulose (OCMC) complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) metal ions have been synthesized and the coordination of OCMC in these complexes has been investigated through IR spectra, reflectance spectra, and thermal analysis. On the basis of spectral and therma...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/820328 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832554564719476736 |
|---|---|
| author | H. D. Juneja Manisha Joshi J. P. Kanfade |
| author_facet | H. D. Juneja Manisha Joshi J. P. Kanfade |
| author_sort | H. D. Juneja |
| collection | DOAJ |
| description | The oxaloyl carboxymethyl cellulose (OCMC) complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) metal ions have been synthesized and the coordination of OCMC in these complexes has been investigated through IR spectra, reflectance spectra, and thermal analysis. On the basis of spectral and thermal data an octahedral geometry was assigned to [Mn(II)OCMC(H2O)2]n and [Co(II)OCMC(H2O)2]n, square planar geometry was assigned to [Cu(II)OCMC]n, and tetrahedral geometry was assigned to [Ni(II)OCMC]n and [Zn(II)OCMC]n Metallic Gel complexes. |
| format | Article |
| id | doaj-art-5287fb901bdf4f9b80948edd43f8b822 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-5287fb901bdf4f9b80948edd43f8b8222025-02-03T05:51:04ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/820328820328Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl CelluloseH. D. Juneja0Manisha Joshi1J. P. Kanfade2Department of Chemistry, Rashtrasant Tukadoji Maharaj Nagpur University, Nagpur 440033, IndiaDepartment of Chemistry, Priyadarshini College of Engineering, Nagpur 440019, IndiaDepartment of Chemistry, Priyadarshini College of Engineering, Nagpur 440019, IndiaThe oxaloyl carboxymethyl cellulose (OCMC) complexes of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) metal ions have been synthesized and the coordination of OCMC in these complexes has been investigated through IR spectra, reflectance spectra, and thermal analysis. On the basis of spectral and thermal data an octahedral geometry was assigned to [Mn(II)OCMC(H2O)2]n and [Co(II)OCMC(H2O)2]n, square planar geometry was assigned to [Cu(II)OCMC]n, and tetrahedral geometry was assigned to [Ni(II)OCMC]n and [Zn(II)OCMC]n Metallic Gel complexes.http://dx.doi.org/10.1155/2013/820328 |
| spellingShingle | H. D. Juneja Manisha Joshi J. P. Kanfade Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose Journal of Chemistry |
| title | Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose |
| title_full | Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose |
| title_fullStr | Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose |
| title_full_unstemmed | Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose |
| title_short | Synthesis and Characterization of Metallic Gel Complexes Derived from Carboxymethyl Cellulose |
| title_sort | synthesis and characterization of metallic gel complexes derived from carboxymethyl cellulose |
| url | http://dx.doi.org/10.1155/2013/820328 |
| work_keys_str_mv | AT hdjuneja synthesisandcharacterizationofmetallicgelcomplexesderivedfromcarboxymethylcellulose AT manishajoshi synthesisandcharacterizationofmetallicgelcomplexesderivedfromcarboxymethylcellulose AT jpkanfade synthesisandcharacterizationofmetallicgelcomplexesderivedfromcarboxymethylcellulose |