Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection

For a long time, metal oxide semiconductor (MOS) based gas sensors have been widely used in domestic, commercial, and industrial sectors to detect harmful gases. The performance of such sensors is significantly enhanced by appropriate doping of suitable materials into MOS such as ZnO and SnO2. This...

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Main Authors: Robin Simkhada, Dalton R. Gibbs, Soma Dhakal, Dipak Oli, Rishi Ram Ghimire, Deependra Das Mulmi, Leela Pradhan Joshi
Format: Article
Language:English
Published: Department of Physics, Mahendra Morang Adarsh Multiple Campus, Tribhuvan University 2025-01-01
Series:Bibechana
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Online Access:https://nepjol.info/index.php/BIBECHANA/article/view/70639
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author Robin Simkhada
Dalton R. Gibbs
Soma Dhakal
Dipak Oli
Rishi Ram Ghimire
Deependra Das Mulmi
Leela Pradhan Joshi
author_facet Robin Simkhada
Dalton R. Gibbs
Soma Dhakal
Dipak Oli
Rishi Ram Ghimire
Deependra Das Mulmi
Leela Pradhan Joshi
author_sort Robin Simkhada
collection DOAJ
description For a long time, metal oxide semiconductor (MOS) based gas sensors have been widely used in domestic, commercial, and industrial sectors to detect harmful gases. The performance of such sensors is significantly enhanced by appropriate doping of suitable materials into MOS such as ZnO and SnO2. This work showcases the design, analysis, and use of a Cu-doped ZnO (Cu: ZnO) film tailored for detecting traces of ethanol vapor at lower temperatures. Herein, various Cu: ZnO films have been fabricated on glass substrates using a spin coater followed by annealing at 600  for 1 hour in a muffle furnace. So-prepared samples have been characterized using X-ray diffraction, Energy Dispersive Analysis X-ray (EDAX), UV-visible spectrophotometer, and Scanning Electron Microscopy (SEM). The XRD analysis showed a polycrystalline nature with preferred orientation along (100) and (002) crystal planes. The morphology study showed their porous and granular surface structure. These films' elemental analysis demonstrated the good incorporation of Cu into the ZnO matrix. The UV-visible results showed a significant decrease in the band gap from 3.28 eV for undoped ZnO to 3.20 eV for Cu: ZnO films. Ultimately, as-prepared Cu: ZnO thin films were used for sensing ethanol vapor at temperatures ranging from 100 to 300 . The result showed a maximum sensitivity of 70.60  at a reduced temperature of 140  at 4% Cu: ZnO thin, which implies that Cu: ZnO is suitable for developing the gas sensors for upcoming future generations.
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language English
publishDate 2025-01-01
publisher Department of Physics, Mahendra Morang Adarsh Multiple Campus, Tribhuvan University
record_format Article
series Bibechana
spelling doaj-art-519eb5ff55004b9da731f5e294d23a962025-01-29T13:15:25ZengDepartment of Physics, Mahendra Morang Adarsh Multiple Campus, Tribhuvan UniversityBibechana2091-07622382-53402025-01-01221Fabrication of Cu: ZnO thin film sensor for ethanol vapor detectionRobin Simkhada0Dalton R. Gibbs1Soma Dhakal2Dipak Oli3Rishi Ram Ghimire4Deependra Das Mulmi5Leela Pradhan Joshi6https://orcid.org/0000-0002-5369-9076Dept. of Physics, Amrit Campus, Tribhuvan University, KathmanduVirginia Commonwealth University, Dept. of Chemistry, Richmond, VA, 23284, USAVirginia Commonwealth University, Dept. of Chemistry, Richmond, VA, 23284, USADept. of Physics, Amrit Campus, Tribhuvan University, KathmanduDept. of Physics, Patan Multiple Campus, Tribhuvan University, KathmanduNanomaterials Research Laboratory, Nepal Academy of Science & Technology, KhumaltarDepartment of Physics, Amrit Campus, Tribhuvan University, Kathmandu, Nepal For a long time, metal oxide semiconductor (MOS) based gas sensors have been widely used in domestic, commercial, and industrial sectors to detect harmful gases. The performance of such sensors is significantly enhanced by appropriate doping of suitable materials into MOS such as ZnO and SnO2. This work showcases the design, analysis, and use of a Cu-doped ZnO (Cu: ZnO) film tailored for detecting traces of ethanol vapor at lower temperatures. Herein, various Cu: ZnO films have been fabricated on glass substrates using a spin coater followed by annealing at 600  for 1 hour in a muffle furnace. So-prepared samples have been characterized using X-ray diffraction, Energy Dispersive Analysis X-ray (EDAX), UV-visible spectrophotometer, and Scanning Electron Microscopy (SEM). The XRD analysis showed a polycrystalline nature with preferred orientation along (100) and (002) crystal planes. The morphology study showed their porous and granular surface structure. These films' elemental analysis demonstrated the good incorporation of Cu into the ZnO matrix. The UV-visible results showed a significant decrease in the band gap from 3.28 eV for undoped ZnO to 3.20 eV for Cu: ZnO films. Ultimately, as-prepared Cu: ZnO thin films were used for sensing ethanol vapor at temperatures ranging from 100 to 300 . The result showed a maximum sensitivity of 70.60  at a reduced temperature of 140  at 4% Cu: ZnO thin, which implies that Cu: ZnO is suitable for developing the gas sensors for upcoming future generations. https://nepjol.info/index.php/BIBECHANA/article/view/70639: PolycrystallinePolycrystallineSpin coatingGas sensorZinc OxideCu:ZnO
spellingShingle Robin Simkhada
Dalton R. Gibbs
Soma Dhakal
Dipak Oli
Rishi Ram Ghimire
Deependra Das Mulmi
Leela Pradhan Joshi
Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection
Bibechana
: Polycrystalline
Polycrystalline
Spin coating
Gas sensor
Zinc Oxide
Cu:ZnO
title Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection
title_full Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection
title_fullStr Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection
title_full_unstemmed Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection
title_short Fabrication of Cu: ZnO thin film sensor for ethanol vapor detection
title_sort fabrication of cu zno thin film sensor for ethanol vapor detection
topic : Polycrystalline
Polycrystalline
Spin coating
Gas sensor
Zinc Oxide
Cu:ZnO
url https://nepjol.info/index.php/BIBECHANA/article/view/70639
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