Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives

This article presents the effect of increasing weight percentage natural nanoclay additives on the structure, morphology and mechanical properties of nylon-6-blown films. Combination of X-ray diffraction, thermal analysis and microscopy were used to determine nanocomposite film morphology. The nanoc...

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Main Authors: Raghavendra R. Hegde, Gajanan S. Bhat, Bhushan Deshpande
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2012/959035
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author Raghavendra R. Hegde
Gajanan S. Bhat
Bhushan Deshpande
author_facet Raghavendra R. Hegde
Gajanan S. Bhat
Bhushan Deshpande
author_sort Raghavendra R. Hegde
collection DOAJ
description This article presents the effect of increasing weight percentage natural nanoclay additives on the structure, morphology and mechanical properties of nylon-6-blown films. Combination of X-ray diffraction, thermal analysis and microscopy were used to determine nanocomposite film morphology. The nanoclay additives in the films act as nucleating agent facilitates γ-crystalline forms and results in fine grained spherulite with smaller lamellar size. Increase in tensile, burst, and tear strength is observed for films with up to 5% clay loading. Even though microscale property like tensile and tear strength drops at higher add on levels, near-surface nanoscale hardness and toughness of the film keep on increasing. There is a direct correlation between nanoclay additive add on level and increase in surface energy and wetting behavior of films.
format Article
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institution Kabale University
issn 1687-9422
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language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-513c891ae7704d4f92ed57d6673eb0132025-02-03T01:33:10ZengWileyInternational Journal of Polymer Science1687-94221687-94302012-01-01201210.1155/2012/959035959035Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay AdditivesRaghavendra R. Hegde0Gajanan S. Bhat1Bhushan Deshpande2Department of Materials Science and Engineering, The University of Tennessee, Knoxville, TN 37996-2200, USADepartment of Materials Science and Engineering, The University of Tennessee, Knoxville, TN 37996-2200, USATechmer PM, Clinton, TN 37716, USAThis article presents the effect of increasing weight percentage natural nanoclay additives on the structure, morphology and mechanical properties of nylon-6-blown films. Combination of X-ray diffraction, thermal analysis and microscopy were used to determine nanocomposite film morphology. The nanoclay additives in the films act as nucleating agent facilitates γ-crystalline forms and results in fine grained spherulite with smaller lamellar size. Increase in tensile, burst, and tear strength is observed for films with up to 5% clay loading. Even though microscale property like tensile and tear strength drops at higher add on levels, near-surface nanoscale hardness and toughness of the film keep on increasing. There is a direct correlation between nanoclay additive add on level and increase in surface energy and wetting behavior of films.http://dx.doi.org/10.1155/2012/959035
spellingShingle Raghavendra R. Hegde
Gajanan S. Bhat
Bhushan Deshpande
Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives
International Journal of Polymer Science
title Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives
title_full Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives
title_fullStr Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives
title_full_unstemmed Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives
title_short Morphology and Properties of Nylon 6 Blown Films Reinforced with Different Weight Percentage of Nanoclay Additives
title_sort morphology and properties of nylon 6 blown films reinforced with different weight percentage of nanoclay additives
url http://dx.doi.org/10.1155/2012/959035
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AT bhushandeshpande morphologyandpropertiesofnylon6blownfilmsreinforcedwithdifferentweightpercentageofnanoclayadditives