Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite

The sorption of manganese(II) and nickel(II) onto two adsorbents, kaolinite and bentonite from aqueous solution was studied in batch mode. Effect of pH, contact time, adsorbent dose, and initial metal ion concentration on adsorption was investigated. The adsorbents exhibit good sorption potential f...

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Main Authors: B. Sathyanarayana, K. Seshaiah
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/985289
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author B. Sathyanarayana
K. Seshaiah
author_facet B. Sathyanarayana
K. Seshaiah
author_sort B. Sathyanarayana
collection DOAJ
description The sorption of manganese(II) and nickel(II) onto two adsorbents, kaolinite and bentonite from aqueous solution was studied in batch mode. Effect of pH, contact time, adsorbent dose, and initial metal ion concentration on adsorption was investigated. The adsorbents exhibit good sorption potential for manganese(II) and nickel(II) with a peak value at pH 5 and pH 6 respectively. More than 70% sorption occurred within 20 min for manganese(II) and nickel(II) and equilibrium was attained at 90 min. for manganese(II) and 120 min for nickel(II). Freundlich and Langmuir's mathematical models were used to describe batch adsorption. The adsorption was found to be favourable with respect to both the isotherms. The adsorption of the two metal ions from aqueous solution onto two adsorbents followed pseudo-second order kinetics.
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institution Kabale University
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spelling doaj-art-5101fb39f61448ecbea9eb1ab63df4fe2025-02-03T06:07:35ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018137338510.1155/2011/985289Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and BentoniteB. Sathyanarayana0K. Seshaiah1Department of Chemistry, S.G.S.A. College, S.V. University, Tirupati-517502, IndiaDepartment of Chemistry, S.V. University, Tirupati-517 502, IndiaThe sorption of manganese(II) and nickel(II) onto two adsorbents, kaolinite and bentonite from aqueous solution was studied in batch mode. Effect of pH, contact time, adsorbent dose, and initial metal ion concentration on adsorption was investigated. The adsorbents exhibit good sorption potential for manganese(II) and nickel(II) with a peak value at pH 5 and pH 6 respectively. More than 70% sorption occurred within 20 min for manganese(II) and nickel(II) and equilibrium was attained at 90 min. for manganese(II) and 120 min for nickel(II). Freundlich and Langmuir's mathematical models were used to describe batch adsorption. The adsorption was found to be favourable with respect to both the isotherms. The adsorption of the two metal ions from aqueous solution onto two adsorbents followed pseudo-second order kinetics.http://dx.doi.org/10.1155/2011/985289
spellingShingle B. Sathyanarayana
K. Seshaiah
Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite
E-Journal of Chemistry
title Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite
title_full Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite
title_fullStr Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite
title_full_unstemmed Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite
title_short Kinetics and Equilibrium Studies on the Sorption of Manganese(II) and Nickel(II) onto Kaolinite and Bentonite
title_sort kinetics and equilibrium studies on the sorption of manganese ii and nickel ii onto kaolinite and bentonite
url http://dx.doi.org/10.1155/2011/985289
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