Reactive dye extraction utilizing regenerated bleaching earth

Bentonite bleaching earth is utilized for purifying used motor oil through a recovery process in order to improve the quality and stability of the final product. Indeed, spent bleaching earth is generated due to adsorbing oil impurities. Polluted spent bleaching earth contains 20-40% (w/w) oil and i...

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Main Authors: M. Shahi, M.R. Sabour, G.A. Dezvareh
Format: Article
Language:English
Published: GJESM Publisher 2017-09-01
Series:Global Journal of Environmental Science and Management
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Online Access:http://www.gjesm.net/article_24425_8004896bae7e5f56a5e221209a16076c.pdf
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author M. Shahi
M.R. Sabour
G.A. Dezvareh
author_facet M. Shahi
M.R. Sabour
G.A. Dezvareh
author_sort M. Shahi
collection DOAJ
description Bentonite bleaching earth is utilized for purifying used motor oil through a recovery process in order to improve the quality and stability of the final product. Indeed, spent bleaching earth is generated due to adsorbing oil impurities. Polluted spent bleaching earth contains 20-40% (w/w) oil and is flammable. Its disposal without pre-treatment leads to loss of oil along with environmental impacts. Accordingly, similar studies have been conducted since 1979 until now. This research was a laboratory study on reactive dye adsorption. Cleaning bleaching clay, thermal remediation and acid washing activation methods were utilized. Response surface methodology was used to design the experiments and determine the optimal parameters in order to run the dye adsorption process. The main experimental parameters have been concluded as temperature (200-800 °C), acid solution concentration (0.1-3 M), dye solution concentration (1-35 ppm), and ratio of activated earth to dye solution (0.1-2 %, w/w). Results revealed that dye adsorption process along with oil removal at a temperature of 650 °C, acid solution concentration of 0.83 M, dye solution concentration of 11.75 ppm and ratio of activated earth to dye solution of 1.52 % (w/w) results in an adsorption efficiency of 68.57%. This removal efficiency is a bit higher than activated virgin bleaching earth and much higher than virgin bleaching earth, which has adsorption capacities of 66.75% and 51.56%, respectively. Considering this recycling process, the purified material is quite acceptable technically, environmentally and economically.
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2383-3866
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series Global Journal of Environmental Science and Management
spelling doaj-art-50b3f910b947463a8ff1b29b7aa4f8ec2025-02-02T15:30:22ZengGJESM PublisherGlobal Journal of Environmental Science and Management2383-35722383-38662017-09-013329931010.22034/gjesm.2017.03.03.00724425Reactive dye extraction utilizing regenerated bleaching earthM. Shahi0M.R. Sabour1G.A. Dezvareh2Department of Civil Engineering, K. N. Toosi University of Technology, Tehran, IranDepartment of Civil Engineering, K. N. Toosi University of Technology, Tehran, IranDepartment of Civil Engineering, K. N. Toosi University of Technology, Tehran, IranBentonite bleaching earth is utilized for purifying used motor oil through a recovery process in order to improve the quality and stability of the final product. Indeed, spent bleaching earth is generated due to adsorbing oil impurities. Polluted spent bleaching earth contains 20-40% (w/w) oil and is flammable. Its disposal without pre-treatment leads to loss of oil along with environmental impacts. Accordingly, similar studies have been conducted since 1979 until now. This research was a laboratory study on reactive dye adsorption. Cleaning bleaching clay, thermal remediation and acid washing activation methods were utilized. Response surface methodology was used to design the experiments and determine the optimal parameters in order to run the dye adsorption process. The main experimental parameters have been concluded as temperature (200-800 °C), acid solution concentration (0.1-3 M), dye solution concentration (1-35 ppm), and ratio of activated earth to dye solution (0.1-2 %, w/w). Results revealed that dye adsorption process along with oil removal at a temperature of 650 °C, acid solution concentration of 0.83 M, dye solution concentration of 11.75 ppm and ratio of activated earth to dye solution of 1.52 % (w/w) results in an adsorption efficiency of 68.57%. This removal efficiency is a bit higher than activated virgin bleaching earth and much higher than virgin bleaching earth, which has adsorption capacities of 66.75% and 51.56%, respectively. Considering this recycling process, the purified material is quite acceptable technically, environmentally and economically.http://www.gjesm.net/article_24425_8004896bae7e5f56a5e221209a16076c.pdfAcid washing activationActivated virgin bleaching earth (AVBE)Reactive dye adsorptionResponse surface methodology (RSM)Spent bleaching earth (SBE)Thermal remediation
spellingShingle M. Shahi
M.R. Sabour
G.A. Dezvareh
Reactive dye extraction utilizing regenerated bleaching earth
Global Journal of Environmental Science and Management
Acid washing activation
Activated virgin bleaching earth (AVBE)
Reactive dye adsorption
Response surface methodology (RSM)
Spent bleaching earth (SBE)
Thermal remediation
title Reactive dye extraction utilizing regenerated bleaching earth
title_full Reactive dye extraction utilizing regenerated bleaching earth
title_fullStr Reactive dye extraction utilizing regenerated bleaching earth
title_full_unstemmed Reactive dye extraction utilizing regenerated bleaching earth
title_short Reactive dye extraction utilizing regenerated bleaching earth
title_sort reactive dye extraction utilizing regenerated bleaching earth
topic Acid washing activation
Activated virgin bleaching earth (AVBE)
Reactive dye adsorption
Response surface methodology (RSM)
Spent bleaching earth (SBE)
Thermal remediation
url http://www.gjesm.net/article_24425_8004896bae7e5f56a5e221209a16076c.pdf
work_keys_str_mv AT mshahi reactivedyeextractionutilizingregeneratedbleachingearth
AT mrsabour reactivedyeextractionutilizingregeneratedbleachingearth
AT gadezvareh reactivedyeextractionutilizingregeneratedbleachingearth