Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater

Synthesis of poly(hydroxamic acid)-poly(amidoxime) chelating ligands were carried out from poly(methyl acrylate-co-acrylonitrile) grafted sago starch and hydroxylamine in alkaline medium. The binding property of metal ions was performed and maximum sorption capacity of the copper was 3.20 mmol/ g an...

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Main Authors: M. R. Lutfor, M. Y. Mashitah
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/645628
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author M. R. Lutfor
M. Y. Mashitah
author_facet M. R. Lutfor
M. Y. Mashitah
author_sort M. R. Lutfor
collection DOAJ
description Synthesis of poly(hydroxamic acid)-poly(amidoxime) chelating ligands were carried out from poly(methyl acrylate-co-acrylonitrile) grafted sago starch and hydroxylamine in alkaline medium. The binding property of metal ions was performed and maximum sorption capacity of the copper was 3.20 mmol/ g and the rate of exchange of some metals was faster, i.e. t½ ≈ 7 min (average). Two types of wastewater containing chromium, zinc, nickel, copper and iron, etc. were used and the heavy metal recovery was found to be highly efficient, about 99% of the metals could be removed from the metal plating wastewater.
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spelling doaj-art-4f067905acf8419884902b8ea7a8dab22025-02-03T06:11:02ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01831038104310.1155/2011/645628Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial WastewaterM. R. Lutfor0M. Y. Mashitah1Faculty of Industrials Sciences and Technology, University Malaysia Pahang, 26300 Gambang, Kuantan, Pahang, MalaysiaFaculty of Industrials Sciences and Technology, University Malaysia Pahang, 26300 Gambang, Kuantan, Pahang, MalaysiaSynthesis of poly(hydroxamic acid)-poly(amidoxime) chelating ligands were carried out from poly(methyl acrylate-co-acrylonitrile) grafted sago starch and hydroxylamine in alkaline medium. The binding property of metal ions was performed and maximum sorption capacity of the copper was 3.20 mmol/ g and the rate of exchange of some metals was faster, i.e. t½ ≈ 7 min (average). Two types of wastewater containing chromium, zinc, nickel, copper and iron, etc. were used and the heavy metal recovery was found to be highly efficient, about 99% of the metals could be removed from the metal plating wastewater.http://dx.doi.org/10.1155/2011/645628
spellingShingle M. R. Lutfor
M. Y. Mashitah
Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
E-Journal of Chemistry
title Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
title_full Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
title_fullStr Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
title_full_unstemmed Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
title_short Synthesis of Poly(hydroxamic Acid)-Poly(amidoxime) Chelating Ligands for Removal of Metals from Industrial Wastewater
title_sort synthesis of poly hydroxamic acid poly amidoxime chelating ligands for removal of metals from industrial wastewater
url http://dx.doi.org/10.1155/2011/645628
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