Kinetic, mechanistic and thermodynamic investigations on Iridium (III) catalyzed oxidation of D-Mannitol by N-chloro-p-toluenesulfonamide in perchloric acid medium

The present paper deals with the kinetics and mechanism of homogeneously Ir(III) chloride catalyzed oxidation of D-mannitol by chloramine-T [CAT] in perchloric acid medium in the temperature range of 30 to 45 0C. The reaction is carried out in the presence of mercuric acetate as a scavenger for chlo...

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Bibliographic Details
Main Authors: J. Pandey, A. Verma, R. Patel, Sh. Srivastava
Format: Article
Language:English
Published: Iranian Association of Chemical Engineering (IAChE) 2017-12-01
Series:Iranian Journal of Chemical Engineering
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Online Access:https://www.ijche.com/article_58604_ebb8cacb072571b0e5fdd47f6914d011.pdf
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