Caffeine content in filter coffee brews as a function of degree of roast and extraction yield

Abstract The effect of degree of roast on resulting caffeine content in brewed coffee has been extensively researched, but conflicting methodologies and results have muddled development of a general conclusion. In this study, 30 unique combinations of green coffee variety, degree of roast, and brew...

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Main Authors: Zachary R. Lindsey, Joshua R. Williams, James S. Burgess, Nathan T. Moore, Pierce M. Splichal
Format: Article
Language:English
Published: Nature Portfolio 2024-11-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-024-80385-3
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author Zachary R. Lindsey
Joshua R. Williams
James S. Burgess
Nathan T. Moore
Pierce M. Splichal
author_facet Zachary R. Lindsey
Joshua R. Williams
James S. Burgess
Nathan T. Moore
Pierce M. Splichal
author_sort Zachary R. Lindsey
collection DOAJ
description Abstract The effect of degree of roast on resulting caffeine content in brewed coffee has been extensively researched, but conflicting methodologies and results have muddled development of a general conclusion. In this study, 30 unique combinations of green coffee variety, degree of roast, and brew time were investigated regarding extraction yield and caffeine content. An AeroPress brewer was used to prepare brew samples using a 15:1 mass ratio of brew water to ground coffee. Refractometry and HPLC were respectively used to measure extraction yield and caffeine content of brewed samples. Scanning electron microscopy was used to measure porosity of roasted seeds and showed increasing porosity with the degree of roast. Extraction yields generally decreased for roast batches with roasting mass losses greater than $$\sim$$ ∼ 12–14%, and caffeine concentrations in 10-min brews decreased for roast batches with drop temperatures greater than $$\sim$$ ∼ 400–420  $$^{\circ }$$ ∘ F. Under identical brewing conditions, caffeine concentrations in brewed samples were generally lower for dark roasts than light and medium roasts. However, at identical extraction yields, dark roasts generally exhibited higher caffeine concentrations than lighter roasted coffees. It is likely that the volatilization or decomposition of soluble compounds and increased porosity due to roasting act as competing mechanisms that determine compound concentrations in resulting brews.
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spelling doaj-art-4e0bbfc37b6b41c285199934d52c4eae2025-08-20T02:08:20ZengNature PortfolioScientific Reports2045-23222024-11-0114111310.1038/s41598-024-80385-3Caffeine content in filter coffee brews as a function of degree of roast and extraction yieldZachary R. Lindsey0Joshua R. Williams1James S. Burgess2Nathan T. Moore3Pierce M. Splichal4Department of Physics, Berry CollegeDepartment of Chemistry, Drexel UniversityDepartment of Chemistry, Berry CollegeDepartment of Physics, Berry CollegeDepartment of Physics, Berry CollegeAbstract The effect of degree of roast on resulting caffeine content in brewed coffee has been extensively researched, but conflicting methodologies and results have muddled development of a general conclusion. In this study, 30 unique combinations of green coffee variety, degree of roast, and brew time were investigated regarding extraction yield and caffeine content. An AeroPress brewer was used to prepare brew samples using a 15:1 mass ratio of brew water to ground coffee. Refractometry and HPLC were respectively used to measure extraction yield and caffeine content of brewed samples. Scanning electron microscopy was used to measure porosity of roasted seeds and showed increasing porosity with the degree of roast. Extraction yields generally decreased for roast batches with roasting mass losses greater than $$\sim$$ ∼ 12–14%, and caffeine concentrations in 10-min brews decreased for roast batches with drop temperatures greater than $$\sim$$ ∼ 400–420  $$^{\circ }$$ ∘ F. Under identical brewing conditions, caffeine concentrations in brewed samples were generally lower for dark roasts than light and medium roasts. However, at identical extraction yields, dark roasts generally exhibited higher caffeine concentrations than lighter roasted coffees. It is likely that the volatilization or decomposition of soluble compounds and increased porosity due to roasting act as competing mechanisms that determine compound concentrations in resulting brews.https://doi.org/10.1038/s41598-024-80385-3
spellingShingle Zachary R. Lindsey
Joshua R. Williams
James S. Burgess
Nathan T. Moore
Pierce M. Splichal
Caffeine content in filter coffee brews as a function of degree of roast and extraction yield
Scientific Reports
title Caffeine content in filter coffee brews as a function of degree of roast and extraction yield
title_full Caffeine content in filter coffee brews as a function of degree of roast and extraction yield
title_fullStr Caffeine content in filter coffee brews as a function of degree of roast and extraction yield
title_full_unstemmed Caffeine content in filter coffee brews as a function of degree of roast and extraction yield
title_short Caffeine content in filter coffee brews as a function of degree of roast and extraction yield
title_sort caffeine content in filter coffee brews as a function of degree of roast and extraction yield
url https://doi.org/10.1038/s41598-024-80385-3
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