Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study

In deep brine oil and gas injection–production operations, the combined long-term effects of brine and carbon dioxide on rock mechanical properties are not clear. In order to solve this problem, the influence of long-term salt–CO<sub>2</sub> environment on the mechanical properties of sa...

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Main Authors: Motao Duan, Haijun Mao, Guangquan Zhang, Junxin Liu, Sinan Zhu, Di Wang, Hao Xie
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/2/607
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author Motao Duan
Haijun Mao
Guangquan Zhang
Junxin Liu
Sinan Zhu
Di Wang
Hao Xie
author_facet Motao Duan
Haijun Mao
Guangquan Zhang
Junxin Liu
Sinan Zhu
Di Wang
Hao Xie
author_sort Motao Duan
collection DOAJ
description In deep brine oil and gas injection–production operations, the combined long-term effects of brine and carbon dioxide on rock mechanical properties are not clear. In order to solve this problem, the influence of long-term salt–CO<sub>2</sub> environment on the mechanical properties of sandstone is discussed. The mechanism of interaction evolution and fracture propagation was studied in detail by NMR, the triaxial compression test and a CT scan. The results show that the triaxial compressive strength and mass of sandstone decrease first and then increase with the prolonging of soaking time. The proportion of micropores first decreased and then increased, while the proportion of medium and large pores first increased and then decreased. The pores obtained by Avizo’s segmentation of the threshold value of CT sections first increased and then decreased, and the fractal dimensions obtained first increased and then decreased. In particular, the calcium ions in the immersion solution increased first and then decreased. The reaction rate was obtained and verified according to the changes in calcium carbonate mass and calcium ion mineralization at different times. The failure mode of the sample gradually changed from /-shaped failure to V-shaped composite failure, then to local /-shaped failure, and finally to X-shaped composite failure. On this basis, the process of sandstone was divided into the dissolution stage, precipitation stage and secondary dissolution stage, and the rock microstructure change model under a salt–CO<sub>2</sub> environment was established. The mechanics, temperature, chemical interaction mechanism and fracture propagation mechanism of sandstone under a salt–CO<sub>2</sub> environment are discussed.
format Article
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institution Kabale University
issn 2076-3417
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publishDate 2025-01-01
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spelling doaj-art-4d8713db5da14090951786020ba521b02025-01-24T13:20:02ZengMDPI AGApplied Sciences2076-34172025-01-0115260710.3390/app15020607Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental StudyMotao Duan0Haijun Mao1Guangquan Zhang2Junxin Liu3Sinan Zhu4Di Wang5Hao Xie6School of Civil Engineering and Architecture, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory of Geomechanics and Geotechnical Engineering, Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan 430071, ChinaChina Petroleum Exploration and Development Research Institute, China Petroleum & Chemical Corporation, Beijing 102206, ChinaSchool of Civil Engineering and Architecture, Southwest University of Science and Technology, Mianyang 621010, ChinaChina Petroleum Exploration and Development Research Institute, China Petroleum & Chemical Corporation, Beijing 102206, ChinaSchool of Civil Engineering and Architecture, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Civil Engineering and Architecture, Southwest University of Science and Technology, Mianyang 621010, ChinaIn deep brine oil and gas injection–production operations, the combined long-term effects of brine and carbon dioxide on rock mechanical properties are not clear. In order to solve this problem, the influence of long-term salt–CO<sub>2</sub> environment on the mechanical properties of sandstone is discussed. The mechanism of interaction evolution and fracture propagation was studied in detail by NMR, the triaxial compression test and a CT scan. The results show that the triaxial compressive strength and mass of sandstone decrease first and then increase with the prolonging of soaking time. The proportion of micropores first decreased and then increased, while the proportion of medium and large pores first increased and then decreased. The pores obtained by Avizo’s segmentation of the threshold value of CT sections first increased and then decreased, and the fractal dimensions obtained first increased and then decreased. In particular, the calcium ions in the immersion solution increased first and then decreased. The reaction rate was obtained and verified according to the changes in calcium carbonate mass and calcium ion mineralization at different times. The failure mode of the sample gradually changed from /-shaped failure to V-shaped composite failure, then to local /-shaped failure, and finally to X-shaped composite failure. On this basis, the process of sandstone was divided into the dissolution stage, precipitation stage and secondary dissolution stage, and the rock microstructure change model under a salt–CO<sub>2</sub> environment was established. The mechanics, temperature, chemical interaction mechanism and fracture propagation mechanism of sandstone under a salt–CO<sub>2</sub> environment are discussed.https://www.mdpi.com/2076-3417/15/2/607sandstoneCO<sub>2</sub> solutionsalinity formulanuclear magnetic resonance (NMR)pore
spellingShingle Motao Duan
Haijun Mao
Guangquan Zhang
Junxin Liu
Sinan Zhu
Di Wang
Hao Xie
Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study
Applied Sciences
sandstone
CO<sub>2</sub> solution
salinity formula
nuclear magnetic resonance (NMR)
pore
title Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study
title_full Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study
title_fullStr Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study
title_full_unstemmed Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study
title_short Saline–CO<sub>2</sub> Solution Effects on the Mechanical Properties of Sandstones: An Experimental Study
title_sort saline co sub 2 sub solution effects on the mechanical properties of sandstones an experimental study
topic sandstone
CO<sub>2</sub> solution
salinity formula
nuclear magnetic resonance (NMR)
pore
url https://www.mdpi.com/2076-3417/15/2/607
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AT junxinliu salinecosub2subsolutioneffectsonthemechanicalpropertiesofsandstonesanexperimentalstudy
AT sinanzhu salinecosub2subsolutioneffectsonthemechanicalpropertiesofsandstonesanexperimentalstudy
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