Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III)
The asymmetric unit of the title organic–inorganic salt, (IC2H4NH3)3[BiI6], consists of a [BiI6]3− octahedron and three 2-iodoethylammonium cations. The octahedra do not interact with each other, and the supramolecular arrangement is ensured by an intricate network of N—H...I hydrogen bonds between...
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International Union of Crystallography
2025-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025000386 |
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| author | Olesia I. Kucheriv Valeriia M. Ovdenko Iryna S. Kuzevanova Irina A. Golenya Il'ya A. Gural'skiy |
| author_facet | Olesia I. Kucheriv Valeriia M. Ovdenko Iryna S. Kuzevanova Irina A. Golenya Il'ya A. Gural'skiy |
| author_sort | Olesia I. Kucheriv |
| collection | DOAJ |
| description | The asymmetric unit of the title organic–inorganic salt, (IC2H4NH3)3[BiI6], consists of a [BiI6]3− octahedron and three 2-iodoethylammonium cations. The octahedra do not interact with each other, and the supramolecular arrangement is ensured by an intricate network of N—H...I hydrogen bonds between cations and anions. In addition, a weak I...I interaction between an organic cation and the coordination octahedron is present in the crystal structure. Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H...I (72.3%) and I...I (11.3%) interactions. |
| format | Article |
| id | doaj-art-4d524831bec6420dbc9d6864c0e816f9 |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-4d524831bec6420dbc9d6864c0e816f92025-02-06T07:27:16ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-02-0181216016310.1107/S2056989025000386wm5745Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III)Olesia I. Kucheriv0Valeriia M. Ovdenko1Iryna S. Kuzevanova2Irina A. Golenya3Il'ya A. Gural'skiy4Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, UkraineDepartment of General and Inorganic Chemistry, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Beresteiskyi Pr. 37, 03056 Kyiv, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, UkraineDepartment of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, UkraineThe asymmetric unit of the title organic–inorganic salt, (IC2H4NH3)3[BiI6], consists of a [BiI6]3− octahedron and three 2-iodoethylammonium cations. The octahedra do not interact with each other, and the supramolecular arrangement is ensured by an intricate network of N—H...I hydrogen bonds between cations and anions. In addition, a weak I...I interaction between an organic cation and the coordination octahedron is present in the crystal structure. Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H...I (72.3%) and I...I (11.3%) interactions.https://journals.iucr.org/paper?S2056989025000386crystal structurebismuth(iii) iodideorganic cationhybrid material |
| spellingShingle | Olesia I. Kucheriv Valeriia M. Ovdenko Iryna S. Kuzevanova Irina A. Golenya Il'ya A. Gural'skiy Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III) Acta Crystallographica Section E: Crystallographic Communications crystal structure bismuth(iii) iodide organic cation hybrid material |
| title | Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III) |
| title_full | Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III) |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III) |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III) |
| title_short | Crystal structure and Hirshfeld surface analysis of the organic–inorganic hybrid compound tris(2-iodoethylammonium) hexaiodidobismuthate(III) |
| title_sort | crystal structure and hirshfeld surface analysis of the organic inorganic hybrid compound tris 2 iodoethylammonium hexaiodidobismuthate iii |
| topic | crystal structure bismuth(iii) iodide organic cation hybrid material |
| url | https://journals.iucr.org/paper?S2056989025000386 |
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